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Catalysts for Fine Chemical Synthesis: Metal Catalysed Carbon-Carbon Bond-Forming Reactions(1)
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scopus(8)
Highly selective barbier-type propargylations and allenylations catalyzed by titanocene(III)
ArticleAbstract: The alkyne functional group is found in many bioactive natural products and is the key to many imporPalabras claves:Allenes, carbonyl compounds, homogeneous catalysis, propargylations, titaniumAutores:Álvarez-Manzaneda E., Antonio Rosales Martínez, Muñoz-Bascón J., Oltra J.E., Sancho-Sanz I.Fuentes:scopusUnprecedented Barbier-type reactions catalysed by titanocene(III)
ArticleAbstract: Selective Barbier-type allylations, benzylations and propargylations of aldehydes and ketones can bePalabras claves:Autores:Antonio Rosales Martínez, Cuerva J.M., Gansäuer A., Justicia J., Oller-López J.L., Oltra J.E.Fuentes:scopusTi-Catalyzed Synthesis of Exocyclic Allenes on Oxygen Heterocycles
ArticleAbstract: A general method for the straightforward synthesis of exocyclic allenes on five-, six-, seven-, andPalabras claves:Allenes, Cyclization, homogeneous catalysis, Oxygen heterocycles, titanium, TitanoceneAutores:Alvarez-Corral M., Antonio Rosales Martínez, García-Martínez M., Hernández-Cervantes C., Muñoz-Bascón J., Muñoz-Dorado M., Oltra J.E., Padial N.M., Rodríguez-García I., Roldan-Molina E., Ruiz-Muelle A.B.Fuentes:scopusTi-catalyzed homolytic opening of ozonides: A sustainable C-C bond-forming reaction
ArticleAbstract: The unprecedented homolytic opening of ozonides promoted and catalyzed by titanocene(III) is reportePalabras claves:Autores:Alvarez-Corral M., Antonio Rosales Martínez, López-Sánchez C., Muñoz-Bascón J., Muñoz-Dorado M., Oltra J.E., Rodríguez-García I.Fuentes:scopusTi-catalyzed straightforward synthesis of exocyclic allenes
ArticleAbstract: Exocyclic allenes constitute useful building blocks in organic synthesis and have recently been idenPalabras claves:Allenes, Cyclization, enantioselectivity, heterocycles, synthetic methods, titaniumAutores:Alvarez-Corral M., Antonio Rosales Martínez, Hernández-Cervantes C., Muñoz-Bascón J., Oltra J.E., Padial N.M., Rodríguez-García I.Fuentes:scopusTitanocene-Catalyzed Cascade Cyclization of Epoxypolyprenes: Straightforward Synthesis of Terpenoids by Free-Radical Chemistry
ArticleAbstract: The titanocene-catalyzed cascade cyclization of epoxypolyenes, which are easily prepared from commerPalabras claves:Cyclization, Domino reactions, homogeneous catalysis, Radical reactions, titaniumAutores:Antonio Rosales Martínez, Bañuel E., Barrero A.F., Cárdenas D., Cuerva J.M., Haïdour A., Justicia J., Oller-López J.L., Oltra J.E., Valdivia M.Fuentes:scopusTitanocene-catalysed transannular cyclisation of epoxygermacrolides: Enantiospecific synthesis of eudesmanolides
Book PartAbstract: This chapter contains sections titled: Molecular sieves as promoters for the catalytic Pauson-KhandPalabras claves:Acetoxypalladation-initiated carbonheteroatom multiple bond insertion-protonolysis system, Alkyne cyclotrimerization, Carbon-carbon multiple bond insertion, Carbon-palladium bond, Carbon-transition-metal bonds, Eudesmanolides, Flash chromatography, Pauson-khand reaction (PKR), Titanocene-catalyzed cyclization of epoxygermacrolidesAutores:Antonio Rosales Martínez, Cuerva J.M., Oltra J.E.Fuentes:scopusTitanocene-catalysed, selective reduction of ketones in aqueous media. A safe, mild, inexpensive procedure for the synthesis of secondary alcohols via radical chemistry
ArticleAbstract: We report here a novel procedure for the reduction of ketones to secondary alcohols using catalyticPalabras claves:electron transfer, Free radicals, homogeneous catalysis, Ketones, titaniumAutores:Antonio Rosales Martínez, Barrero A.F., Cuerva J.M., Gansäuer A., Oltra J.E.Fuentes:scopus