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Unified synthesis of eudesmanolides, combining biomimetic strategies with homogeneous catalysis and free-radical chemistry
ArticleAbstract: (Matrix presented) A general procedure for the synthesis of both 12,6- and 12,8-eudesmanolides has bPalabras claves:Autores:Antonio Rosales Martínez, Barrero A.F., Cuerva J.M., Oltra J.E.Fuentes:scopusTitanocene-catalysed, selective reduction of ketones in aqueous media. A safe, mild, inexpensive procedure for the synthesis of secondary alcohols via radical chemistry
ArticleAbstract: We report here a novel procedure for the reduction of ketones to secondary alcohols using catalyticPalabras claves:electron transfer, Free radicals, homogeneous catalysis, Ketones, titaniumAutores:Antonio Rosales Martínez, Barrero A.F., Cuerva J.M., Gansäuer A., Oltra J.E.Fuentes:scopus