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A rare example of extremely strong carbon—carbon coupling: Analysis of <sup>13</sup>C and <sup>1</sup>H NMR spectra of a <sup>13</sup>C<inf>2</inf>‐acetylenic ketone
ArticleAbstract: NMR spectra are reported for an acetylenic ketone enriched with 13C in the acetylenic carbon atoms tPalabras claves:AB/ABX spin system, INADEQUATE acetylenic ketones, strong carbon‐carbon couplingAutores:Covey D.F., d'Avignon A., Richard J. AuchusFuentes:scopusDehydrogenase Inactivation by an Enzyme-Generated Acetylenic Ketone: Identification of a Lysyl Enaminone by<sup>13</sup>C NMR
ArticleAbstract:Palabras claves:Autores:Covey D.F., Richard J. AuchusFuentes:scopusMechanism-Based Inactivation of 17β,20α-Hydroxysteroid Dehydrogenase by an Acetylenic Secoestradiol
ArticleAbstract: 14,15-Secoestra-1,3,5(10)-trien-15-yne-3,17β-diol (1) is a mechanism-based inactivator of human placPalabras claves:Autores:Covey D.F., Richard J. AuchusFuentes:scopusPreparation of 14,15-secoestra-1,3,5(10)-trien-15-ynes, inhibitors of estradiol dehydrogenase
ArticleAbstract: The conversion of estrone to 14,15-secoestratrien-15-ynes, inactivators of estradiol dehydrogenase fPalabras claves:Autores:Carrell H.L., Covey D.F., Palmer J.O., Richard J. AuchusFuentes:scopusThe 5-hydroxyl of myo-inositol is essential for uptake into HSDM<inf>1</inf>C<inf>1</inf> mouse fibrosarcoma cells
ArticleAbstract: We attempted to replace the myo-inositol in cellular inositol phosphatides with 5-deoxy-myo-inositolPalabras claves:Autores:Covey D.F., Majerus P.W., Richard J. Auchus, Wilson D.B.Fuentes:scopusThe enantiomer of progesterone (ent-progesterone) is a competitive inhibitor of human cytochromes P450c17 and P450c21
ArticleAbstract: Human cytochrome P450c17 (17α-hydroxylase, 17,20-lyase) (CYP17) and cytochrome P450c21 (21-hydroxylaPalabras claves:17α-Hydroxylase/17,20-lyase, 21-hydroxylase, CYP17, CYP21, Cytochrome P450c17, Cytochrome P450c21, ent-Progesterone, Enzyme inhibition, molecular dynamics, Type I difference spectrumAutores:Boswell C., Bruce K., Covey D.F., Gupta M.K., Kumar A., Rath N., Richard J. AuchusFuentes:scopus