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Synthesis of rhenacyclopentadienes and η<sup>2</sup>:η<sup>2</sup>-diyne complexes from a labile dirhenium carbonyl and π-conjugated 1,7-octadiynes: Structural and photophysical characterization
ArticleAbstract: A series of dirhenium carbonyl compounds containing π-conjugated diyne ligands and symmetrical 2,5-bPalabras claves:1,7-octadiynes, Dirhenium carbonyls, Fluorescent rhenacyclopentadiene, photophysical properties, π-conjugated diyneAutores:Arce A.J., Cardozo C., Farías G., Formiga A.L.B., Fuentes F., Mendoza A., Peña D., Yomaira OteroFuentes:scopusSynthesis, characterization and reactivity of dinuclear rhenium complexes containing hemilabile phosphines as ligands: X-ray structures of diax-[Re<inf>2</inf>(CO)<inf>8</inf>{κ<sup>1</sup>(P)-Ph<inf>2</inf>P(CH<inf>2</inf>)<inf>2</inf>CN}<inf>2</inf>], [Re<inf>2</inf>(CO)<inf>8</inf>{μ:κ<sup>3</sup>(P,C,C)-<sup>i</sup>Pr<inf>2</inf>NP(CH<inf>2</inf>CH=CH<inf>2</inf>)<inf>2</inf>}] and diax-[Re<inf>2</inf>(CO)<inf>8</inf>(PPh<inf>3</inf>){κ<sup>1</sup>(P)-p-MeOC<inf>6</inf>H<inf>4</inf>P(CH<inf>2</inf>CH=CH<inf>2</inf>)<inf>2</inf>}]
ArticleAbstract: The reaction of [Re2(CO)8(MeCN)2] with cyanoethylphosphines affords mono- and disubstituted compoundPalabras claves:Diallylphosphines, Dinuclear rhenium, Dirhenium carbonyls, Hemilability, IsomerismAutores:Arce A.J., David Santiago Coll, Garcia J.M., Gonzalez T., MacHado R.A., Ocando-Mavárez E., Peña D., Yomaira OteroFuentes:scopus