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"Naked" Ga<sup>+</sup> and In<sup>+</sup> as pure acceptor ligands: Structure and bonding of [GaPt(GaCp*)<inf>4</inf>][BAr <sup>F</sup>]
ArticleAbstract: In the buff: The reaction of [Pt(GaCp*)4] with the Ga + source [Ga2Cp*][BArF] (Cp* = C5Me5; BArF = BPalabras claves:Density functional calculations, Gallium, Group 13 elements, metalloids, PlatinumAutores:Buchin B., Fernandez I., Fischer R.A., Frenking G., Gemel C., Thomas CadenbachFuentes:scopusOrganometallic chemistry of Ga<sup>+</sup>: Formation of an unusual gallium dimer in the coordination sphere of ruthenium
ArticleAbstract: New insights into the distinct organometallic chemistry of the Ga + ion are presented. Ga+ reacts asPalabras claves:Density functional calculations, Gallium, Low-valent ion, metal-metal interactions, rutheniumAutores:Bollermann T., Fernandez I., Fischer R.A., Frenking G., Gemel C., Thomas CadenbachFuentes:googlescopusMethylgallium as a terminal ligand in [(Cp*Ga) <inf>4</inf>Rh(GaCH<inf>3</inf>)]<sup>+</sup>
ArticleAbstract: (Chemical Presented) The smallest possible gallium alkyl species, the otherwise elusive GaCH3, has bPalabras claves:Carbenoids, Gallium, Metal ligands, Oxidation states, RhodiumAutores:Fischer R.A., Gemel C., Thomas Cadenbach, Zacher D.Fuentes:googlescopusMolecular cut-outs of Mo/Zn hume-rothery phases: Synthesis and structure of [{Mo(CO)<inf>4</inf>}<inf>4</inf>(Zn)<inf>6</inf>(μ-ZnCp*) <inf>4</inf>]
ArticleAbstract: Zinc in the middle: The reaction of [Mo-(GaCp*)2(CO) 4] and Zn(CH3)2 results in the cluster [{Mo(CO)Palabras claves:cluster compounds, Coordination chemistry, Gallium, Molybdenum, ZincAutores:Fischer R.A., Gemel C., Thomas CadenbachFuentes:scopusTwelve one-electron ligands coordinating one metal center: Structure and bonding of [Mo(ZnCH<inf>3</inf>)<inf>9</inf>(ZnCp*)<inf>3</inf>]
ArticleAbstract: Surrounded by zinc: The reaction of [Mo-(GaCp*)6] and Zn(CH3)2 zinc yields the exceptionally high-coPalabras claves:cluster compounds, Coordination chemistry, Gallium, Molybdenum, ZincAutores:Bollermann T., Fernandez I., Fischer R.A., Frenking G., Gemel C., Thomas Cadenbach, Von Hopffgarten M.Fuentes:googlescopusSubstituent-free gallium by hydrogenolysis of coordinated gaCp*: Synthesis and structure of highly fluxional [Ru<inf>2</inf>(Ga)(GaCp*) <inf>7</inf>(H)<inf>3</inf>]
ArticleAbstract: All change: Complete ligand exchange through the hydrogenation of [Ru(η4-cod)(η6-cot)] in the presenPalabras claves:cluster compounds, Coordination chemistry, Gallium, Hydrogenolysis, rutheniumAutores:Cokoja M., Fischer R.A., Gemel C., Halbherr M., Schmid R., Thomas Cadenbach, Yusenko K.Fuentes:scopusThe [Ga<inf>2</inf>(C<inf>5</inf>Me<inf>5</inf>)]<sup>+</sup> ion: Bipyramidal double-cone structure and weakly coordinated, monovalent Ga <sup>+</sup>
ArticleAbstract: (Figure Presented) Partial protolysis of GaCp* with [H-(OEt 2)2]+[BArF]- afforded the GaI compound [Palabras claves:Carbenoids, Cyclopentadienyl compounds, Gallium, Group 13 elementsAutores:Buchin B., Fischer R.A., Gemel C., Schmid R., Thomas CadenbachFuentes:scopus