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Organometallic chemistry of Ga<sup>+</sup>: Formation of an unusual gallium dimer in the coordination sphere of ruthenium
ArticleAbstract: New insights into the distinct organometallic chemistry of the Ga + ion are presented. Ga+ reacts asPalabras claves:Density functional calculations, Gallium, Low-valent ion, metal-metal interactions, rutheniumAutores:Bollermann T., Fernandez I., Fischer R.A., Frenking G., Gemel C., Thomas CadenbachFuentes:googlescopusMethylgallium as a terminal ligand in [(Cp*Ga) <inf>4</inf>Rh(GaCH<inf>3</inf>)]<sup>+</sup>
ArticleAbstract: (Chemical Presented) The smallest possible gallium alkyl species, the otherwise elusive GaCH3, has bPalabras claves:Carbenoids, Gallium, Metal ligands, Oxidation states, RhodiumAutores:Fischer R.A., Gemel C., Thomas Cadenbach, Zacher D.Fuentes:googlescopusMolecular cut-outs of Mo/Zn hume-rothery phases: Synthesis and structure of [{Mo(CO)<inf>4</inf>}<inf>4</inf>(Zn)<inf>6</inf>(μ-ZnCp*) <inf>4</inf>]
ArticleAbstract: Zinc in the middle: The reaction of [Mo-(GaCp*)2(CO) 4] and Zn(CH3)2 results in the cluster [{Mo(CO)Palabras claves:cluster compounds, Coordination chemistry, Gallium, Molybdenum, ZincAutores:Fischer R.A., Gemel C., Thomas CadenbachFuentes:scopusTwelve one-electron ligands coordinating one metal center: Structure and bonding of [Mo(ZnCH<inf>3</inf>)<inf>9</inf>(ZnCp*)<inf>3</inf>]
ArticleAbstract: Surrounded by zinc: The reaction of [Mo-(GaCp*)6] and Zn(CH3)2 zinc yields the exceptionally high-coPalabras claves:cluster compounds, Coordination chemistry, Gallium, Molybdenum, ZincAutores:Bollermann T., Fernandez I., Fischer R.A., Frenking G., Gemel C., Thomas Cadenbach, Von Hopffgarten M.Fuentes:googlescopus