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(S)-Selectivity in Phenylacetyl Carbinol Synthesis Using the Wild-Type Enzyme Acetoin:Dichlorophenolindophenol Oxidoreductase from Bacillus licheniformis
ArticleAbstract: Thiamine diphosphate (ThDP)-dependent enzymes are well known biocatalysts for the asymmetric synthesPalabras claves:Asymmetric synthesis, C−C coupling, enzyme catalysis, thiamine diphosphate, umpolungAutores:Bastiani M.D., Catani M., Di Carmine G., Giovanni Bernacchia, Giovannini P.P., Lerin L.A., Massi A., Müller M.Fuentes:scopusEnzymatic Chemoselective Aldehyde-Ketone Cross-Couplings through the Polarity Reversal of Methylacetoin
ArticleAbstract: Abstract The thiamine diphosphate (ThDP) dependent enzyme acetoin:dichlorophenolindophenol oxidoreduPalabras claves:Asymmetric synthesis, enzyme catalysis, oxidoreductases, tertiary alcohols, thiamine diphosphateAutores:Bortolini O., De Bastiani M., Giovanni Bernacchia, Giovannini P.P., Lerin L.A., Loschonsky S., Massi A., Müller M.Fuentes:scopusEnzymatic Cross-Benzoin-Type Condensation of Aliphatic Aldehydes: Enantioselective Synthesis of 1-Alkyl-1-hydroxypropan-2-ones and 1-Alkyl-1-hydroxybutan-2-ones
ArticleAbstract: Benzoin-type reactions have been intensively exploited as a synthetic strategy for the preparation oPalabras claves:Asymmetric synthesis, C−C coupling, enzyme catalysis, thiamine diphosphate, umpolungAutores:Bortolini O., Di Carmine G., Fantin G., Giovanni Bernacchia, Giovannini P.P., Massi A., Müller M., Ragno D.Fuentes:scopus