Mostrando 10 resultados de: 38
Publisher
Inorganica Chimica Acta(5)
Journal of Computational Methods in Sciences and Engineering(4)
Applied Surface Science(2)
Computational and Theoretical Chemistry(2)
Journal of Physical Chemistry C(2)
Área temáticas
Química física(24)
Química inorgánica(17)
Química orgánica(10)
Ingeniería y operaciones afines(6)
Química analítica(6)
Área de conocimiento
Ciencia de materiales(17)
Ingeniería química(7)
Química teórica(7)
Catálisis(6)
Química inorgánica(4)
Chemistry of transition-metal complexes containing functionalized phosphines. Part 2. Cationic rhodium(I) complexes stabilized by hemilabile diallylphosphines
ArticleAbstract: Cationic rhodium(I) complexes of the type [Rh(COD){κ<sup>3</sup>(P,C, C)-RP(CH<inf>2</inf>CHCH<inf>2Palabras claves:Diallylphosphines, Hemilabile properties, Hybrid ligands, Ligand exchange reactionAutores:Ascanio J., Atencio R., Bricẽo A., David Santiago Coll, Edward E. Ávila, Garcia J.M., Gonzalez T., Ocando-Mavárez E., Pekerar S.V., Rosales M., Teresa GonzálezFuentes:googlescopusA novel tetramer copper(I) complex containing diallylphosphine ligands: Synthesis, characterization and catalytic application in A3-coupling (Aldehyde-Amine-Alkyne) reactions
ArticleAbstract: A novel tetrameric copper(I) complex containing tert-butyldiallylphosphine ligands, [CuCl{<sup>t</suPalabras claves:A -coupling reactions 3, A3-coupling reactions, Diallylphosphine ligands, Propargylamine, Tetramer cobre(I) complexAutores:David Santiago Coll, Edward E. Ávila, Garcia J.M., Gonzalez T., Ocando-Mavárez E., Rosales J., Teresa GonzálezFuentes:googlescopusA simple method for the determination of the Tolman electronic parameter of different phosphorus containing ligands, by means of the average local ionization energy
ArticleAbstract: Abstract The average local ionization energy (I(r)) was tested as a theoretical descriptor of the ToPalabras claves:Average local ionization energy, Cone angle, Electrostatic potential, Phosphines and Phosphites basicity, Tolman electronic parameterAutores:Alba Beatriz Vidal, Añez R., David Santiago Coll, Ocando-Mavárez E., Rodríguez J.A., Sierraalta A.Fuentes:scopusThe kinetics and mechanism of the homogeneous, unimolecular gas-phase elimination of 2-(4-substituted-phenoxy)tetrahydro-2H-pyranes
ArticleAbstract: The gas-phase elimination kinetics of tetrahydropyranyl phenoxy ethers: 2-phenoxytetrahydro-2H-pyranPalabras claves:Autores:Alexis Maldonado, Alvarez-Aular A., Cartaya L., Chuchania G., David Santiago Coll, Maldonado A.Fuentes:scopusThermodynamics and Conformational Dynamics of Primer Nucleotide Sequences Associated with Monkeypox Virus (MpxV): Comparative Analysis of Stability and Specificity with a Biophysical-Computational Approach
ArticleAbstract: COVID-19 pandemic has shown the need to detect new pathogens quickly. Currently, attention has beenPalabras claves:molecular dynamics, OPG, orthopoxviruses, primers, SWAXS curveAutores:Alvarado Y.J., David Santiago Coll, González-Paz L.A., Hurtado-León M.L., Jeffreys L.N., Joan Vera-Villalobos, José Luis Paz, Lossada C.A., Yovani Marrero-PonceFuentes:googlescopusStability of intermediates in the glycerol hydrogenolysis on transition metal catalysts from first principles
ArticleAbstract: The hydrogenolysis reaction catalyzed by a transition metal solid catalyst is a potential way to traPalabras claves:Autores:David Santiago Coll, Delbecq F., Sautet P., Yosslen R. ArayFuentes:scopusStudy of the Reaction Mechanism of Triazines and Associated Species for H2S Scavenging
ArticleAbstract: Natural gas produced worldwide contains, among other compounds, H<inf>2</inf>S and CO<inf>2</inf>. BPalabras claves:Autores:David Santiago Coll, Díaz M.A., Román M.N.Fuentes:scopusSynthesis and characterization of rhodium complexes with phosphine-stabilized germylenes
ArticleAbstract: The reaction of phosphine-stabilized germylenes (1a,b) with dimer complex [Rh <inf>2</inf>(μ-Cl) <inPalabras claves:Autores:Baceiredo A., Bricẽo A., David Santiago Coll, Garcia J.M., Kato T., Ocando-Mavárez E., Saffon-Merceron N.Fuentes:scopusSynthesis, characterization and biological activity of platinum(II) complexes with a tetrapyrazole ligand
ArticleAbstract: In the search of an effective chemotherapy for the treatment of cancer, in this work we describe thePalabras claves:anticancer activity, DNA, Platinum complexes, Tetrapyrazole ligand, Thioredoxin reductaseAutores:Capote J., Castro W., David Santiago Coll, Fernández-Mestre M., Hernández-Medina F., Higuera-Padilla A.R., Karam A.R., Ortega D., Rodriguez B., Rodriguez-Cordero M., Taylor P., Urdanibia I.Fuentes:scopusSynthesis, characterization and reactivity of dinuclear rhenium complexes containing hemilabile phosphines as ligands: X-ray structures of diax-[Re2(CO)8{κ1(P)-Ph2P(CH2)2CN}2], [Re2(CO)8{μ:κ3(P,C,C)-iPr2NP(CH2CH=CH2)2}] and diax-[Re2(CO)8(PPh3){κ1(P)-p-MeOC6H4P(CH2CH=CH2)2}]
ArticleAbstract: The reaction of [Re<inf>2</inf>(CO)<inf>8</inf>(MeCN)<inf>2</inf>] with cyanoethylphosphines affordsPalabras claves:Diallylphosphines, Dinuclear rhenium, Dirhenium carbonyls, Hemilability, IsomerismAutores:Arce A.J., David Santiago Coll, Garcia J.M., Gonzalez T., MacHado R.A., Ocando-Mavárez E., Peña D., Teresa González, Yomaira OteroFuentes:scopus