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A new complex of copper-phosphole. Synthesis, characterization and evaluation of biological activity
ArticleAbstract: As part of the search for effective cancer chemotherapy, we describe here the synthesis, characterizPalabras claves:Cytotoxicity, DNA, Metal–phosphole complexes, Phosphole, ThioredoxinAutores:Alba Beatriz Vidal, Alfonso S., Castro W., Fernández M., González S., Higuera-Padilla A.R., Reiber A., Taylor P., Urdanibia I., Yomaira OteroFuentes:scopusFluxional behaviour of phosphole and phosphine ligands on triosmium clusters
ArticleAbstract: The unsaturated cluster [Os<inf>3</inf>(μ-H)<inf>2</inf>(CO)<inf>10</inf>] reacts with a variety ofPalabras claves:Fluxional behavior, Mono- and disubstituted triosmium, Phosphine, Phosphole, Unsaturated osmium clusterAutores:Arce A.J., De Sanctis Y., Gonzalez T., Hissler M., MacHado R.A., Ocando-Mavárez E., Peña D., Réau R., Yomaira OteroFuentes:scopusHigh versatility of 3,4-dimethyl-1-phenyl-phosphole and 3-methyl-1-phenyl-phosphole as ligands in the reaction with [Re 2(CO)8(CH3CN)2] and [Ru3(CO)12]: X-ray structures of [Re2(CO)7(1:2:2-PhPC 4H2Me2)], [Re2(CO)7(1:2:2-PhPC4H3Me)] and [Ru2(CO)4(PhPC <inf>4</inf>H<inf>3</inf>Me)<inf>2</inf>]
ArticleAbstract: The reaction of [Re2(CO)8(CH3CN) 2] with 3,4-dimethyl-1-phenylphosphole affords three chromatographiPalabras claves:Dinuclear rhenium, Phospholes, Sandwich complexes, Triruthenium cluster, σ-π complexAutores:Arce A.J., Bricẽo A., De Sanctis Y., Goite M.C., Gonzalez T., MacHado R.A., Yomaira OteroFuentes:scopusInsertion of a phospholide unit into a metal-metal bond: Synthesis and X-ray structure of [Ru<inf>3</inf>(CO)<inf>9</inf>(μ:η<sup>1</sup>: η<sup>5</sup>-PC<inf>4</inf>H<inf>2</inf>Me<inf>2</inf>)(η<sup>1</sup>- C<inf>6</inf>H<inf>5</inf>)]
ArticleAbstract: The reaction of [Ru3(CO)12] with 3,4-dimethyl-1- phenylphosphole under mild conditions affords threePalabras claves:Phospholes, Phospholide, Triosmium clusters, Triruthenium clustersAutores:Arce A.J., De Sanctis Y., Goite M.C., Gonzalez T., MacHado R.A., Yomaira OteroFuentes:scopusReaction of carbonyl trinuclear clusters with 2,5-bis(2-thienyl)-1-phenyl-phosphole as a ligand: A new pathway to ruthenacyclopentadiene and cyclopentadienone ruthenium complexes
ArticleAbstract: [Ru3(CO)12] reacts with 2,5-bis(2-thienyl)-1-phenyl-phosphole (btpp) in refluxing CH2Cl2 to afford mPalabras claves:Autores:Arce A.J., Edward E. Ávila, Hissler M., Lescop C., MacHado R.A., Peña D., Réau R., Yomaira OteroFuentes:scopusReactivity of dirhenium and triruthenium carbonyls toward a biphosphole ligand: M–M, P–P and C–H bonds cleavage
ArticleAbstract: The reaction of [Re2(CO)8(CH3CN)2] with bis(2-thienyl)biphosphole in refluxing n-octane affords thePalabras claves:Biphosphole, C-H activation, Metal-metal and phosphorus-phosphorus bonds cleavage, Tetranuclear cluster, η -phospholyl complex 5Autores:Arce A.J., David Santiago Coll, Edward E. Ávila, Fuentes F., Gonzalez T., Hissler M., MacHado R.A., Peña D., Réau R., Yomaira OteroFuentes:googlescopusReactivity of triosmium clusters with 3,4-dimethyl-1-phenylphosphole and cyanoethyldi-tert-butylphosphine ligands: X-ray crystal structures of [Os <inf>3</inf>(CO)<inf>9</inf>(μ-OH)(μ-H)(η<sup>1</sup>-PhPC <inf>4</inf>H<inf>2</inf>Me<inf>2</inf>)] and [Os<inf>3</inf>(CO) <inf>11</inf>(η<sup>1</sup>- <sup>t</sup> Bu<inf>2</inf>PC<inf>2</inf>H <inf>4</inf>CN)]
ArticleAbstract: Reaction of [Os3(μ-H)2(CO)10] with 3,4-dimethyl-1-phenylphosphole in refluxing cyclohexane affords tPalabras claves:Autores:Arce A.J., De Sanctis Y., Gonzalez T., MacHado R.A., Ocando-Mavárez E., Peña D., Yomaira OteroFuentes:scopusSynthesis and characterization of trinuclear osmium clusters containing diallylphosphines as hemilabile ligands: Experimental and theoretical studies of their reactivity with nucleophilic molecules
ArticleAbstract: A series of [Os3(CO)12] phosphine substituted derivatives containing alkenylphosphine ligands has bePalabras claves:Allene insertion, Diallylphosphines, Hemilabile phosphines, Triosmium carbonylsAutores:Arce A.J., De Sanctis Y., Díaz L., Garcia J.M., Gonzalez T., MacHado R.A., Ocando-Mavárez E., Peña D., Yomaira OteroFuentes:scopusSynthesis, characterization and reactivity of dinuclear rhenium complexes containing hemilabile phosphines as ligands: X-ray structures of diax-[Re<inf>2</inf>(CO)<inf>8</inf>{κ<sup>1</sup>(P)-Ph<inf>2</inf>P(CH<inf>2</inf>)<inf>2</inf>CN}<inf>2</inf>], [Re<inf>2</inf>(CO)<inf>8</inf>{μ:κ<sup>3</sup>(P,C,C)-<sup>i</sup>Pr<inf>2</inf>NP(CH<inf>2</inf>CH=CH<inf>2</inf>)<inf>2</inf>}] and diax-[Re<inf>2</inf>(CO)<inf>8</inf>(PPh<inf>3</inf>){κ<sup>1</sup>(P)-p-MeOC<inf>6</inf>H<inf>4</inf>P(CH<inf>2</inf>CH=CH<inf>2</inf>)<inf>2</inf>}]
ArticleAbstract: The reaction of [Re2(CO)8(MeCN)2] with cyanoethylphosphines affords mono- and disubstituted compoundPalabras claves:Diallylphosphines, Dinuclear rhenium, Dirhenium carbonyls, Hemilability, IsomerismAutores:Arce A.J., David Santiago Coll, Garcia J.M., Gonzalez T., MacHado R.A., Ocando-Mavárez E., Peña D., Yomaira OteroFuentes:scopus