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Comparative NMR and MS studies on the mechanism of enantioseparation of propranolol with heptakis(2,3-diacetyl-6-sulfo)-β-cyclodextrin in capillary electrophoresis with aqueous and non-aqueous electrolytes
ArticleAbstract: In our recent studies, the reversal of the enantiomer migration order (EMO) was observed with heptakPalabras claves:CE, cyclodextrins, enantiomer migration order, Propranolol, Separation mechanismsAutores:Antonio López J., Antonio Salgado, Calvo E., Chankvetadze B., Lomsadze K.Fuentes:scopusAbout the role of enantioselective selector-selectand interactions and the mobilities of diastereomeric associates in enantiomer separations using CE
ArticleAbstract: It is generally accepted that the selective binding of enantiomers of the chiral analyte to a chiralPalabras claves:CdS, enantiomer migration order, Ketoconazole, Separation mechanisms, TerconazoleAutores:Antonio Salgado, Castro-Puyana M., Chankvetadze B., Chankvetadze L., Crego A.L., Lomsadze K., Marina M.L., Martínez-Girón A.B.Fuentes:scopusNuclear magnetic resonance to study the interactions acting in the enantiomeric separation of homocysteine by capillary electrophoresis with a dual system of γ-cyclodextrin and the chiral ionic liquid EtCholNTf<inf>2</inf>
ArticleAbstract: The enantiomeric separation of 9-fluorenylmethoxycarbonyl chloride (FMOC)-homocysteine (Hcy) by CE wPalabras claves:capillary electrophoresis, Chiral ionic liquids, homocysteine, NMRAutores:Antonio Salgado, Castro-Puyana M., Greño M., Marina M.L.Fuentes:scopusInvestigation on the enantioseparation of duloxetine by capillary electrophoresis, NMR, and mass spectrometry
ArticleAbstract: The enantiomeric separation of the antidepressant drug duloxetine was investigated by CE using 15 nePalabras claves:capillary electrophoresis, cyclodextrins, Duloxetine, enantiomer migration order, Separation mechanismAutores:Antonio Salgado, Crego A.L., Marina M.L., Sánchez-López E.Fuentes:scopusSeparation of enantiomers of norephedrine by capillary electrophoresis using cyclodextrins as chiral selectors: Comparative CE and NMR studies
ArticleAbstract: In this study, the enantiomer migration order (EMO) of norephedrine (NEP) in the presence of variousPalabras claves:Analyte-selector complexes, cyclodextrins, enantiomer migration order, Enantioseparation, NorephedrineAutores:Antonio Salgado, Chankvetadze B., Crego A.L., Lomsadze K., Marina M.L., Scriba G.K.E., Vega E.D.Fuentes:scopusSeparation of propranolol enantiomers by CE using sulfated β-CD derivatives in aqueous and non-aqueous electrolytes: Comparative CE and NMR study
ArticleAbstract: Separations using CE employing non-aqueous BGE are already as well established as separations in aquPalabras claves:Aqueous and non-aqueous CE, CdS, enantiomer migration order, Propranolol, Separation mechanismsAutores:Antonio Salgado, Chankvetadze B., Crommen J., Fillet M., Lomsadze K., Rousseau A., Servais A.Fuentes:scopusSeparation of terbutaline enantiomers in capillary electrophoresis with neutral cyclodextrin-type chiral selectors and investigation of the structure of selector-selectand complexes using nuclear magnetic resonance spectroscopy
ArticleAbstract: The major goal of this study was to determine the affinity pattern of the terbutaline (TB) enantiomePalabras claves:cyclodextrins, enantiomer migration order, selector–selectand complexes, separation of enantiomers, terbutalineAutores:Antonio Salgado, Chankvetadze B., Chankvetadze L., Gogolashvili A., Takaishvili N.Fuentes:scopusThe first contribution of capillary electrophoresis to the study of abiotic origins of homochirality: Investigation of the enantioselective adsorption of 3-carboxy adipic acid on minerals
ArticleAbstract: CE with UV detection was used for the first time to determine the enantioselective adsorption of thePalabras claves:capillary electrophoresis, Homochirality, minerals, Short-chain tricarboxylic acidAutores:Alegre M.L.M., Antonio Salgado, Castro-Puyana M., Crego A.L., Hazen R.M.Fuentes:scopus