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Intramolecular general base catalysis in the hydrolysis of a phosphate diester. calculational guidance to a choice of mechanism
ArticleAbstract: Notwithstanding its half-life of 70 years at 25 C, the spontaneous hydrolysis of the anion of di-2-pPalabras claves:Autores:Amer A., Jose R. Mora, Kirby A.J., Medeiros M., Nome F., Oliveira P., Williams N.Fuentes:googlescopusMajor mechanistic differences between the reactions of hydroxylamine with phosphate di- and tri-esters
ArticleAbstract: Hydroxylamine reacts as an oxygen nucleophile, most likely via its ammonia oxide tautomer, towards bPalabras claves:Autores:Jose R. Mora, Kirby A.J., Medeiros M., Moreira R., Nome F., Wanderlind E.H.Fuentes:googlescopusPolymers containing imidazole groups as nanoreactors for hydrolysis of esters
Conference ObjectAbstract: A polymer (PAIM) containing the functional groups imidazole and carboxylic acid acts as a nanoreactoPalabras claves:carboxylate esters, Catalysis, Hydrolysis, phosphate esters, polymersAutores:Ferreira N., Fiedler H.D., Giusti L., Jose R. Mora, Medeiros M.Fuentes:googlescopus