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Major mechanistic differences between the reactions of hydroxylamine with phosphate di- and tri-esters
ArticleAbstract: Hydroxylamine reacts as an oxygen nucleophile, most likely via its ammonia oxide tautomer, towards bPalabras claves:Autores:Jose R. Mora, Kirby A.J., Medeiros M., Moreira R., Nome F., Wanderlind E.H.Fuentes:googlescopusIntramolecular general base catalysis in the hydrolysis of a phosphate diester. calculational guidance to a choice of mechanism
ArticleAbstract: Notwithstanding its half-life of 70 years at 25 C, the spontaneous hydrolysis of the anion of di-2-pPalabras claves:Autores:Amer A., Jose R. Mora, Kirby A.J., Medeiros M., Nome F., Oliveira P., Williams N.Fuentes:googlescopus