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Homogeneous Reactions of Thiophenes with Transition Metals: A Modeling Approach for Elucidation of the Hydrodesulfurization Mechanism and an Effective Method for the Synthesis of Unusual Organosulfur Compounds
ArticleAbstract: The fragment [(triphos)RhH], generated by thermolysis of (triohos)RhH3(1) in refluxing THF, reacts wPalabras claves:Autores:Bianchini C., Fbkp_rediani P., Herrera V., Jiménez M., Luis Rincon, Meli A., Sánchez-Delgado R.A., Vizza F.Fuentes:googlescopusMolecular Analogs of Surface Species. 3. The Mechanism of the Regioselective Homogeneous Hydrogenation of Benzothiophene by Use of [Rh(COD)(PPh<inf>3</inf>)<inf>2</inf>]PF<inf>6</inf> as the Catalyst Precursor. Kinetic and Theoretical Study
ArticleAbstract: The mechanism of the regioselective hydrogenation of benzo[b]thiophene (BT) to 2,3- dihydrobenzo[b]tPalabras claves:Autores:Andriollo A., Herrera V., Luis Rincon, Martín G., Sánchez-Delgado R.A.Fuentes:scopusTheoretical Study of the Pyramidal Geometry around the Sulfur in the S-Bound Mode of Coordination of Thiophene to the [Cp(CO)<inf>2</inf>Fe]<sup>+</sup> Fragment
ArticleAbstract: Density functional calculations have been carried out to study the pyramidal coordination of the sulPalabras claves:Autores:Guenzburger D., Luis Rincon, Sánchez-Delgado R.A., Terra J.Fuentes:googlescopus