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Fluxional behaviour of phosphole and phosphine ligands on triosmium clusters
ArticleAbstract: The unsaturated cluster [Os<inf>3</inf>(μ-H)<inf>2</inf>(CO)<inf>10</inf>] reacts with a variety ofPalabras claves:Fluxional behavior, Mono- and disubstituted triosmium, Phosphine, Phosphole, Unsaturated osmium clusterAutores:Arce A.J., De Sanctis Y., Gonzalez T., Hissler M., MacHado R.A., Ocando-Mavárez E., Peña D., Réau R., Yomaira OteroFuentes:scopusSynthesis and characterization of trinuclear osmium clusters containing diallylphosphines as hemilabile ligands: Experimental and theoretical studies of their reactivity with nucleophilic molecules
ArticleAbstract: A series of [Os3(CO)12] phosphine substituted derivatives containing alkenylphosphine ligands has bePalabras claves:Allene insertion, Diallylphosphines, Hemilabile phosphines, Triosmium carbonylsAutores:Arce A.J., De Sanctis Y., Díaz L., Garcia J.M., Gonzalez T., MacHado R.A., Ocando-Mavárez E., Peña D., Yomaira OteroFuentes:scopus