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Effects of solvents and water in Ti(III)-mediated radical cyclizations of epoxygermacrolides. Straightforward synthesis and absolute stereochemistry of (+)-3α-hydroxyreynosin and related eudesmanolides
ArticleAbstract: The Cp2TiCl-mediated rearrangement of 1,10-epoxy-11β,13-dihydrocostunolide (4) was carried out usingPalabras claves:Autores:Antonio Rosales Martínez, Barrero A.F., Cuerva J.M., Enrique Oltra J.Fuentes:scopusTitanocene-catalysed, selective reduction of ketones in aqueous media. A safe, mild, inexpensive procedure for the synthesis of secondary alcohols via radical chemistry
ArticleAbstract: We report here a novel procedure for the reduction of ketones to secondary alcohols using catalyticPalabras claves:electron transfer, Free radicals, homogeneous catalysis, Ketones, titaniumAutores:Antonio Rosales Martínez, Barrero A.F., Cuerva J.M., Gansäuer A., Oltra J.E.Fuentes:scopus