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Titanocene-Catalyzed Cascade Cyclization of Epoxypolyprenes: Straightforward Synthesis of Terpenoids by Free-Radical Chemistry
ArticleAbstract: The titanocene-catalyzed cascade cyclization of epoxypolyenes, which are easily prepared from commerPalabras claves:Cyclization, Domino reactions, homogeneous catalysis, Radical reactions, titaniumAutores:Antonio Rosales Martínez, Bañuel E., Barrero A.F., Cárdenas D., Cuerva J.M., Haïdour A., Justicia J., Oller-López J.L., Oltra J.E., Valdivia M.Fuentes:scopusTitanocene-catalysed, selective reduction of ketones in aqueous media. A safe, mild, inexpensive procedure for the synthesis of secondary alcohols via radical chemistry
ArticleAbstract: We report here a novel procedure for the reduction of ketones to secondary alcohols using catalyticPalabras claves:electron transfer, Free radicals, homogeneous catalysis, Ketones, titaniumAutores:Antonio Rosales Martínez, Barrero A.F., Cuerva J.M., Gansäuer A., Oltra J.E.Fuentes:scopus