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Advanced Synthesis and Catalysis(1)
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scopus(6)
A One-Pot Two-Step Enzymatic Pathway for the Synthesis of Enantiomerically Enriched Vicinal Diols
ArticleAbstract: Enantiomerically enriched 1,2-diols are prominent compounds that find numerous applications in organPalabras claves:1,2-Diols, Biocatalysis, One-pot, Stereselective reductions, umpolungAutores:Baraldi S., Bortolini O., Di Carmine G., Giovanni Bernacchia, Giovannini P.P., Jacoby C., Müller M., Presini F., Ragno D.Fuentes:scopusEnzymatic Chemoselective Aldehyde-Ketone Cross-Couplings through the Polarity Reversal of Methylacetoin
ArticleAbstract: Abstract The thiamine diphosphate (ThDP) dependent enzyme acetoin:dichlorophenolindophenol oxidoreduPalabras claves:Asymmetric synthesis, enzyme catalysis, oxidoreductases, tertiary alcohols, thiamine diphosphateAutores:Bortolini O., De Bastiani M., Giovanni Bernacchia, Giovannini P.P., Lerin L.A., Loschonsky S., Massi A., Müller M.Fuentes:scopusEnzymatic Cross-Benzoin-Type Condensation of Aliphatic Aldehydes: Enantioselective Synthesis of 1-Alkyl-1-hydroxypropan-2-ones and 1-Alkyl-1-hydroxybutan-2-ones
ArticleAbstract: Benzoin-type reactions have been intensively exploited as a synthetic strategy for the preparation oPalabras claves:Asymmetric synthesis, C−C coupling, enzyme catalysis, thiamine diphosphate, umpolungAutores:Bortolini O., Di Carmine G., Fantin G., Giovanni Bernacchia, Giovannini P.P., Massi A., Müller M., Ragno D.Fuentes:scopusMicrowave-assisted enzymatic synthesis of geraniol esters in solvent-free systems: optimization of the reaction parameters, purification and characterization of the products, and biocatalyst reuse
ArticleAbstract: Various geraniol esters act as insect pheromones and display pharmacological activities, especiallyPalabras claves:Geranyl (R)-3-hydroxybutyrate, Geranyl acetoacetate, Geranyl butyrate, Geranyl hexanoate, Geranyl octanoate, Lipozyme 435Autores:Bortolini O., Claudio Trapella, Giovannini P.P., Lerin L.A., Presini F., Valentina VenturiFuentes:scopusAn enzymatic approach to the synthesis of optically pure (3R)- and (3S)-enantiomers of green tea flavor compound 3-hydroxy-3-methylnonane-2,4-dione
ArticleAbstract: Both (3R)- and (3S)-enantiomers of the chiral green tea flavor compound 3-hydroxy-3-methylnonane-2,4Palabras claves:Chiral flavor compounds, Enzymatic carboligation, KetoreductaseAutores:Bortolini O., Giovannini P.P., Maietti S., Massi A., Pedrini P., Sacchetti G., Valentina VenturiFuentes:scopusα-Diketones as acyl anion equivalents: A non-enzymatic thiamine-promoted route to aldehyde-ketone coupling in PEG400 as recyclable medium
ArticleAbstract: By mimicking the peculiar behavior of thiamine diphosphate-dependent acetylacetoin synthase, it hasPalabras claves:N-Heterocyclic carbenes, Polyethylene glycol, Thiazolium salts, α-Diketones, α-HydroxyketonesAutores:Bortolini O., Fantin G., Giovannini P.P., Marco Fogagnolo, Massi A., Salvatore Pacifico, Valentina VenturiFuentes:scopus