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Hexafluoroacetone as a protecting and activating reagent. N- and O-glycosylation of isoserine and isocysteine *
ArticleAbstract: Starting from HFA-protected malic and thiomalic acid a series of O- and N-glycoconjugates suitable fPalabras claves:Glycoconjugates, Glycosylamines, Hexafluoroacetone, Isocyanates, malic acid, Thiomalic acidAutores:Alberício F., Böttcher C., Burger K., Hennig L., Jan SpenglerFuentes:googlescopusOrthogonally protected, carboxy-activated L-homoisoserine, 2-methyl-L-homoisoserine, and homoisocysteine derivatives. New building blocks for peptide and depsipeptide modification
ArticleAbstract: Starting from L-malic, L-citramalic, and rac. thiomalic acids routes to L-homoisoserine, 2-methyl-L-Palabras claves:Arndt-Eistert reaction, Azapeptides, Citramalic acid, Curtius rearrangement, Depsipeptide modification, Hexafluoroacetone, malic acid, Peptide modification, Thiomalic acid, Wolff rearrangement, α-Hydroxy acids, α-Mercapto acids, γ-Amino acidsAutores:Alberício F., Böttcher C., Burger K., Hennig L., Jan Spengler, Radics G.Fuentes:googlescopusIncorporation of the α-mercapto acid unit into peptides
ArticleAbstract: Incorporation of α-mercapto acid units into the backbone of potential drug candidates improves the mPalabras claves:Acylations, Dielectrophiles, Hexafluoroacetone, Peptides, Thiols, Thiomalic acidAutores:Alberício F., Burger K., Haas A., Jan Spengler, Pumpor K.Fuentes:googlescopus