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Homogeneous catalysis on the gas-phase dehydration reaction of tertiary alcohols by hydrogen bromide. Density functional theory calculation
Conference ObjectAbstract: The gas-phase thermal dehydration mechanism of tert-butanol, 2-methyl-2-butanol, 2-methyl-2-pentanolPalabras claves:2-methyl-2-butanol, 2-methyl-2-pentanol and 2,3-dimethyl-2-butanol, DFT calculations, Gas-phase thermal decomposition, HBr catalysis, tert-butanolAutores:Brusco Y., Chuchania G., Córdova-Sintjago T.C., Jose R. Mora, Maldonado A., Rosas F.Fuentes:googlescopusKinetics and mechanisms of gas-phase decarbonylation of α-methyl-trans-cinamaldehyde and E-2-methyl-2-pentenal under homogeneous catalysis of hydrogen chloride
ArticleAbstract: The kinetics of the gas-phase elimination of α-methyl-trans- cinamaldehyde catalyzed by HCl in the tPalabras claves:E-2-methyl-2-pentenal, Gas-phase elimination, kinetics, α-methyl-trans-cinamaldehydeAutores:Chuchania G., Jose R. Mora, Julio L.L., Lezama J., Maldonado A.Fuentes:scopusThe mechanisms of the homogeneous, unimolecular, elimination kinetics of several β-substituted diethyl acetals in the gas-phase
ArticleAbstract: The rates of gas-phase elimination of several β-substituted diethyl acetals have been determined inPalabras claves:1,1-diethoxyethane, 1,1-diethoxypropane, 1-(2,2-diethoxyethyl)piperidine, 2-chloro-1,1-diethoxyethane, Gasphase elimination, kinetics, mechanismAutores:Chuchania G., Dominguez R.M., Jose R. Mora, Maldonado A.Fuentes:scopus