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About the role of enantioselective selector-selectand interactions and the mobilities of diastereomeric associates in enantiomer separations using CE
ArticleAbstract: It is generally accepted that the selective binding of enantiomers of the chiral analyte to a chiralPalabras claves:CdS, enantiomer migration order, Ketoconazole, Separation mechanisms, TerconazoleAutores:Antonio Salgado, Castro-Puyana M., Chankvetadze B., Chankvetadze L., Crego A.L., Lomsadze K., Marina M.L., Martínez-Girón A.B.Fuentes:scopusCapillary electrophoretic and nuclear magnetic resonance studies on the opposite affinity pattern of propranolol enantiomers towards various cyclodextrins
ArticleAbstract: In the present study the migration order of the propranolol enantiomers with various native CDs andPalabras claves:capillary electrophoresis, cyclodextrins, enantiomer migration order, NMR spectroscopy, Propranolol, Separation mechanismsAutores:Antonio Salgado, Chankvetadze B., Crommen J., Fillet M., Lomsadze K., Rousseau A., Servais A.Fuentes:scopusComparative NMR and MS studies on the mechanism of enantioseparation of propranolol with heptakis(2,3-diacetyl-6-sulfo)-β-cyclodextrin in capillary electrophoresis with aqueous and non-aqueous electrolytes
ArticleAbstract: In our recent studies, the reversal of the enantiomer migration order (EMO) was observed with heptakPalabras claves:CE, cyclodextrins, enantiomer migration order, Propranolol, Separation mechanismsAutores:Antonio López J., Antonio Salgado, Calvo E., Chankvetadze B., Lomsadze K.Fuentes:scopusComparative enantioseparation of ketoprofen with trimethylated α-, β-, and γ-cyclodextrins in capillary electrophoresis and study of related selector-selectand interactions using nuclear magnetic resonance spectroscopy
ArticleAbstract: The enantiomers of ketoprofen were separated by capillary electrophoresis using the (2,3,6-tri-O-metPalabras claves:1D ROESY, capillary electrophoresis, cyclodextrins, enantiomer affinity pattern, ketoprofen, nuclear magnetic resonance spectroscopy, Separation mechanismAutores:Antonio Salgado, Chankvetadze B., Samakashvili S., Scriba G.K.E.Fuentes:scopusComparative enantioseparation of talinolol in aqueous and non-aqueous capillary electrophoresis and study of related selector-selectand interactions by nuclear magnetic resonance spectroscopy
ArticleAbstract: The enantiomers of the chiral β-blocker drug talinolol were separated with two single component sulfPalabras claves:Aqueous and non-aqueous capillary electrophoresis, cyclodextrins, Enantioseparations, nuclear magnetic resonance spectroscopy, Reversal of enantiomer migration orderAutores:Antonio Salgado, Chankvetadze B., Chankvetadze L., Crommen J., Fillet M., Servais A.Fuentes:scopusComplexation of daclatasvir by single isomer methylated β-cyclodextrins studied by capillary electrophoresis, NMR spectroscopy and mass spectrometry
ArticleAbstract: In capillary electrophoresis an enantioseparation of daclatasvir (DCV) was observed in case of heptaPalabras claves:capillary electrophoresis, Complex stoichiometry, Complex structure, Cyclodextrin-analyte complexation, Mass spectrometry, nuclear magnetic resonance spectroscopyAutores:Antonio Salgado, Benkovics G., Chankvetadze B., Krait S., Malanga M., Naumann L., Neusüß C., Peluso P., Scriba G.K.E., Sohajda T.Fuentes:scopusStructural characterization of methyl-β-cyclodextrins by high-performance liquid chromatography and nuclear magnetic resonance spectroscopy and effect of their isomeric composition on the capillary electrophoresis enantioseparation of daclatasvir
ArticleAbstract: The separation of daclatasvir and its R,R,R,R-enantiomer was studied by capillary electrophoresis usPalabras claves:capillary electrophoresis, Cyclodextrin isomers, Degree of substitution, enantiomer migration order, Enantioseparation, Methyl-β-cyclodextrinAutores:Antonio Salgado, Benkovics G., Chankvetadze B., Krait S., Malanga M., Scriba G.K.E., Sohajda T., Szakály P.S.Fuentes:scopusStructural rationale for the chiral separation and migration order reversal of clenpenterol enantiomers in capillary electrophoresis using two different β-cyclodextrins
ArticleAbstract: NMR spectroscopy experiments, molecular dynamics simulations, and theoretical chemistry calculationsPalabras claves:Autores:Antonio Salgado, Chankvetadze B., Gago F., Gogolashvili A., Tatunashvili E.Fuentes:scopusSeparation of enantiomers of norephedrine by capillary electrophoresis using cyclodextrins as chiral selectors: Comparative CE and NMR studies
ArticleAbstract: In this study, the enantiomer migration order (EMO) of norephedrine (NEP) in the presence of variousPalabras claves:Analyte-selector complexes, cyclodextrins, enantiomer migration order, Enantioseparation, NorephedrineAutores:Antonio Salgado, Chankvetadze B., Crego A.L., Lomsadze K., Marina M.L., Scriba G.K.E., Vega E.D.Fuentes:scopusSeparation of propranolol enantiomers by CE using sulfated β-CD derivatives in aqueous and non-aqueous electrolytes: Comparative CE and NMR study
ArticleAbstract: Separations using CE employing non-aqueous BGE are already as well established as separations in aquPalabras claves:Aqueous and non-aqueous CE, CdS, enantiomer migration order, Propranolol, Separation mechanismsAutores:Antonio Salgado, Chankvetadze B., Crommen J., Fillet M., Lomsadze K., Rousseau A., Servais A.Fuentes:scopus