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Comparative NMR and MS studies on the mechanism of enantioseparation of propranolol with heptakis(2,3-diacetyl-6-sulfo)-β-cyclodextrin in capillary electrophoresis with aqueous and non-aqueous electrolytes
ArticleAbstract: In our recent studies, the reversal of the enantiomer migration order (EMO) was observed with heptakPalabras claves:CE, cyclodextrins, enantiomer migration order, Propranolol, Separation mechanismsAutores:Antonio López J., Antonio Salgado, Calvo E., Chankvetadze B., Lomsadze K.Fuentes:scopusCarbohydrate-Based Biopolymers: Biologically Active Poly[3-(3,4-Dihydroxyphenyl)Glyceric Acid] from Borago officinalis
ArticleAbstract: A high-molecular water-soluble preparation from stems of Borago officinalis (Boraginaceae family) waPalabras claves:Borago officinalis, caffeic acid-derived polyether, Carbohydrate-based biopolymers, Poly[3-(3,4-dihydroxyphenyl)glyceric acid], poly[oxy-1-carboxy-2-(3,4-dihydroxyphenyl)ethylene]Autores:Amiranashvili L., Antonio Salgado, Barbakadze V., Chankvetadze B., Churadze M., Gogilashvili L., Gogolashvili A., Merlani M.Fuentes:scopusNovel biologically active dihydroxycinnamate-derived polyether from different species of family Boraginaceae
ArticleAbstract: Plants belonging to Boraginaceae family such as Symphytum asperum, S.caucasicum, S.officinale and AnPalabras claves:Anchusa, Boraginaceae, Dihydroxycinnamate-derived polyether, NMR, Poly[3-(3,4-dihydroxyphenyl)glyceric acid], poly[oxy-1-carboxy-2-(3,4-dihydroxyphenyl)ethylene], SymphytumAutores:Amiranashvili L., Antonio Salgado, Barbakadze V., Chankvetadze B., Gogilashvili L., Merlani M., Mulkijanyan K.Fuentes:scopusInvestigation of the complexation between cyclodextrins and medetomidine enantiomers by capillary electrophoresis, NMR spectroscopy and molecular modeling
ArticleAbstract: The migration order of the enantiomers of medetomidine in the presence of cyclodextrins studied by cPalabras claves:Cyclodextrin, enantiomer migration order, molecular modeling, Nuclear magnetic resonance, Selector-selectand complexationAutores:Antonio Salgado, Chankvetadze B., Gago F., Krait S., Scriba G.K.E.Fuentes:scopusIsothermal titration calorimetry and molecular modeling study of the complex formation of daclatasvir by γ-cyclodextrin and trimethyl-β-cyclodextrin
ArticleAbstract: The complex formation between daclatasvir and γ-CD or heptakis(2,3,6-tri-O-methyl)-β-CD (TM-β-CD) waPalabras claves:Complex stoichiometry, Cyclodextrin complexes, Daclatasvir, isothermal titration calorimetry, Molecular dynamics simulationAutores:Antonio Salgado, Chankvetadze B., Dallocchio R., Dessì A., Krait S., Landy D., Nakhle L., Peluso P., Scriba G.K.E.Fuentes:scopusUnusual complexation behavior between daclatasvir and γ-Cyclodextrin. A multiplatform study
ArticleAbstract: During a screening of cyclodextrins (CDs) as chiral selectors for the separation of daclatasvir (DCVPalabras claves:capillary electrophoresis, Complex stoichiometry, Complex structure, Cyclodextrin, Nuclear magnetic resonance, Selector-selectand complexationAutores:Antonio Salgado, Chankvetadze B., Krait S., Naumann L., Neusüß C., Scriba G.K.E., Villani C.Fuentes:scopusSeparation of propranolol enantiomers by CE using sulfated β-CD derivatives in aqueous and non-aqueous electrolytes: Comparative CE and NMR study
ArticleAbstract: Separations using CE employing non-aqueous BGE are already as well established as separations in aquPalabras claves:Aqueous and non-aqueous CE, CdS, enantiomer migration order, Propranolol, Separation mechanismsAutores:Antonio Salgado, Chankvetadze B., Crommen J., Fillet M., Lomsadze K., Rousseau A., Servais A.Fuentes:scopusSeparation of terbutaline enantiomers in capillary electrophoresis with neutral cyclodextrin-type chiral selectors and investigation of the structure of selector-selectand complexes using nuclear magnetic resonance spectroscopy
ArticleAbstract: The major goal of this study was to determine the affinity pattern of the terbutaline (TB) enantiomePalabras claves:cyclodextrins, enantiomer migration order, selector–selectand complexes, separation of enantiomers, terbutalineAutores:Antonio Salgado, Chankvetadze B., Chankvetadze L., Gogolashvili A., Takaishvili N.Fuentes:scopusSeparation of tetrahydrozoline enantiomers in capillary electrophoresis with cyclodextrin-type chiral selectors and investigation of chiral recognition mechanisms
ArticleAbstract: The recognition power and affinity pattern of various cyclodextrins (CD) towards the enantiomers ofPalabras claves:capillary electrophoresis, Chiral recognition mechanism, cyclodextrins, molecular modeling, nuclear magnetic resonance spectroscopy, TetrahydrozolineAutores:Antonio Salgado, Chankvetadze B., Chankvetadze L., Dallocchio R., Gogolashvili A., Lomsadze K., Peluso P., Takaishvili N.Fuentes:scopusPoly[3-(3,4-dihydroxyphenyl)glyceric acid] from Anchusa italica roots
ArticleAbstract: Elucidation of the main structural unit of a water-soluble, high-molecular weight preparation from tPalabras claves:Anchusa italica, Boraginaceae, Caffeic acid-derived polymer, Chemotaxonomic marker, Poly[3-(3,4-dihydroxyphenyl)glyceric acid], poly[oxy-1-carboxy-2-(3,4-dihydroxyphenyl)ethylene], Structure elucidationAutores:Amiranashvili L., Antonio Salgado, Barbakadze V., Chankvetadze B., Churadze M., Gogilashvili L., Merlani M., Mulkijanyan K.Fuentes:scopus