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Effects of solvents and water in Ti(III)-mediated radical cyclizations of epoxygermacrolides. Straightforward synthesis and absolute stereochemistry of (+)-3α-hydroxyreynosin and related eudesmanolides
ArticleAbstract: The Cp2TiCl-mediated rearrangement of 1,10-epoxy-11β,13-dihydrocostunolide (4) was carried out usingPalabras claves:Autores:Antonio Rosales Martínez, Barrero A.F., Cuerva J.M., Enrique Oltra J.Fuentes:scopusUnified synthesis of eudesmanolides, combining biomimetic strategies with homogeneous catalysis and free-radical chemistry
ArticleAbstract: (Matrix presented) A general procedure for the synthesis of both 12,6- and 12,8-eudesmanolides has bPalabras claves:Autores:Antonio Rosales Martínez, Barrero A.F., Cuerva J.M., Oltra J.E.Fuentes:scopusSynthesis of (+)-8-deoxyvernolepin and its 11,13-dihydroderivative. A novel reaction initiated by sulfene elimination leads to the 2-oxa-cis-decalin skeleton
ArticleAbstract: The title compounds are interesting candidates for antifungal screening. This paper describes the enPalabras claves:Autores:Álvarez M., Antonio Rosales Martínez, Barrero A.F., Oltra J.E.Fuentes:scopusTitanocene-Catalyzed Cascade Cyclization of Epoxypolyprenes: Straightforward Synthesis of Terpenoids by Free-Radical Chemistry
ArticleAbstract: The titanocene-catalyzed cascade cyclization of epoxypolyenes, which are easily prepared from commerPalabras claves:Cyclization, Domino reactions, homogeneous catalysis, Radical reactions, titaniumAutores:Antonio Rosales Martínez, Bañuel E., Barrero A.F., Cárdenas D., Cuerva J.M., Haïdour A., Justicia J., Oller-López J.L., Oltra J.E., Valdivia M.Fuentes:scopus