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Chemistry of transition-metal complexes containing functionalized phosphines. Part 2. Cationic rhodium(I) complexes stabilized by hemilabile diallylphosphines
ArticleAbstract: Cationic rhodium(I) complexes of the type [Rh(COD){κ<sup>3</sup>(P,C, C)-RP(CH<inf>2</inf>CHCH<inf>2Palabras claves:Diallylphosphines, Hemilabile properties, Hybrid ligands, Ligand exchange reactionAutores:Ascanio J., Atencio R., Bricẽo A., David Santiago Coll, Edward E. Ávila, Garcia J.M., Gonzalez T., Ocando-Mavárez E., Pekerar S.V., Rosales M., Teresa GonzálezFuentes:googlescopusSynthesis and characterization of trinuclear osmium clusters containing diallylphosphines as hemilabile ligands: Experimental and theoretical studies of their reactivity with nucleophilic molecules
ArticleAbstract: A series of [Os<inf>3</inf>(CO)<inf>12</inf>] phosphine substituted derivatives containing alkenylphPalabras claves:Allene insertion, Diallylphosphines, Hemilabile phosphines, Triosmium carbonylsAutores:Arce A.J., De Sanctis Y., Díaz L., Garcia J.M., Gonzalez T., Lenin Díaz, MacHado R.A., Ocando-Mavárez E., Peña D., Teresa González, Yomaira OteroFuentes:scopusSynthesis, characterization and reactivity of dinuclear rhenium complexes containing hemilabile phosphines as ligands: X-ray structures of diax-[Re2(CO)8{κ1(P)-Ph2P(CH2)2CN}2], [Re2(CO)8{μ:κ3(P,C,C)-iPr2NP(CH2CH=CH2)2}] and diax-[Re2(CO)8(PPh3){κ1(P)-p-MeOC6H4P(CH2CH=CH2)2}]
ArticleAbstract: The reaction of [Re<inf>2</inf>(CO)<inf>8</inf>(MeCN)<inf>2</inf>] with cyanoethylphosphines affordsPalabras claves:Diallylphosphines, Dinuclear rhenium, Dirhenium carbonyls, Hemilability, IsomerismAutores:Arce A.J., David Santiago Coll, Garcia J.M., Gonzalez T., MacHado R.A., Ocando-Mavárez E., Peña D., Teresa González, Yomaira OteroFuentes:scopus