Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire


Abstract:

New coordination complexes of the neutral tripodal tetra-amine Me 6TREN with tBu 3Ga or tBu 2Zn have been synthesised and studied with their molecular structures revealing, for the first time, coordination to metal centres via an η 1 or η 2 mode, adding to previously reported η 3 and η 4 ligated examples. © 2012 The Royal Society of Chemistry.

Año de publicación:

2012

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    Tipo de documento:

    Article

    Estado:

    Acceso restringido

    Áreas de conocimiento:

      Áreas temáticas:

      • Química analítica