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Design and Development of a Catalytic Fixed-Bed Reactor for Gasification of Banana Biomass in Hydrogen Production

Abstract:

Hydrogen produced from biomass is an alternative energy source to fossil fuels. In this study, hydrogen production by gasification of the banana plant is proposed. A fixed-bed catalytic reactor was designed considering fluidization conditions and a height/diameter ratio of 3/1. Experimentation was carried out under the following conditions: 368◦C, atmospheric pressure, 11.75 g of residual mass of the banana (pseudo-stem), an average particle diameter of 1.84 mm, and superheated water vapor as a gasifying agent. Gasification reactions were performed using a catalyzed and uncatalyzed medium to compare the effectiveness of each case. The catalyst was Ni/Al2O3, synthesized by coprecipitation. The gas mixture produced from the reaction was continuously condensed to form a two-phase liquid–gas system. The synthesis gas was passed through a silica gel filter and analyzed online by gas chromatography. To conclude, the results of this study show production of 178 mg of synthesis gas for every 1 g of biomass and the selectivity of hydrogen to be 51.8 mol% when a Ni 2.5% w/w catalyst was used. The amount of CO2 was halved, and CO was reduced from 3.87% to 0% in molar percentage. Lastly, a simulation of the distribution of temperatures inside the furnace was developed; the modeled behavior is in agreement with experimental observations.