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Development and characterization of an inorganic foam obtained by using sodium bicarbonate as a gas generator

Abstract:

In the construction industry almost all of the insulating and expansive materials are organic foams. In this work, the production of an inorganic foam is described. Sodium bicarbonate is used as a gas generator. CO2 gas is released when water is added to the mixture of sodium bicarbonate and β-hemihydrate gypsum powder (CaSO4 • 1/2H2O). Hence, stabilization of the foam is achieved when CO2 gas is released and water is absorbed by β-hemihydrate gypsum powder, which subsequently is converted into calcium sulphate dihydrate (gypsum matrix). The bulk density and mechanical properties (compressive and flexural strength) of the inorganic foam and gypsum were determined. Microstructural characterization has been carried out by SEM and XRD, and a new sodium sulphate phase was identified in the gypsum foam due to this chemical reaction. Finally, thermal properties such as thermal conductivity and diffusivity were measured and it was observed how for the same heat flux, the thickness of an inorganic foam slab is 73.4% less than that of a concrete slab. © 2005 Elsevier Ltd. All rights reserved.