Hydrogen atom donors: Recent developments

Abstract:

This review highlights recent developments in the field of hydrogen atom transfer (HAT) reagents that circumvent the disadvantages of classical group 14 reagents, such as Bu 3SnH. Special emphasis is laid on the lowering of bond dissociation energies (BDEs) of molecules that could, as yet, not be used as HAT reagents and on the use of organometallic HAT reagents. © 2011 Springer-Verlag Berlin Heidelberg.

Año de publicación:

2012

Keywords:

• Bond dissociation energies
• Hydrogen atom transfer
• radicals
• Chain reactions
• Metal-hydrogen bonds
• Catalysis

Fuente:

scopus