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Identification of biodegradable polymers as contaminants in the thermoplastics recycling process

Abstract:

In this work, the presence of biodegradable polymers in recycled plastic materials was characterized using readily available techniques. Recycled polypropylene (PP), polystyrene (PS), and polyethylene terephthalate (PET) were studied. The contamination of these plastics with polylactic acid (PLA), polyhydroxybutyrate (PHB), and thermoplastic starch (TPS) was simulated using 10wt.% of the contaminant. Fourier transform infrared spectrometry (FTIR) and differential scanning calorimetry (DSC) were used as characterization techniques. In addition, the effect of aging on recycled products from PET blends contaminated with TPS and PHB was studied. The results show changes in the intensity of the FTIR spectra bands of the PS and PP blends contaminated with biodegradable polymers. By DSC, changes in the cold crystallization peak of recycled PET are observed when mixed with TPS and PHB. When the contaminant is PLA, the changes are masked due to the thermal characteristics of both materials. In PS, changes in the calorimetric curves are identified by the presence of PLA and PHB. Contamination with PLA, PHB, and TPS hinders the processing of recycled PET after one year of storage due to the aging of the material.