Induced self-assembly of a tetrathiafulvalene-based open-shell dyad through intramolecular electron transfer

Abstract:

An organic switch: An open-shell dyad, consisting of an electron acceptor perchlorotriphenylmethyl radical unit linked to an electron π-donor tetrathiafulvalene unit through a vinylene π-bridge, was synthesized (see picture). The self-assembly of the dyad in solution induced by its intramolecular electron transfer was studied. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Año de publicación:

2012

Keywords:

• radicals
• ESR spectroscopy
• Supramolecular chemistry
• self-assembly
• electron transfer

Fuente:

scopus