One electron organozinc ligands in metal rich molecules by Ga/Zn exchange: From Cp*Rh(GaCp*)<inf>2</inf> to Cp*Rh(ZnR)<inf>4</inf> units

Abstract:

Two unusual compounds, [{Cp*Rh(ZnCp*)2(ZnMe)(ZnCl)} 2] (1) and [Cp*2Rh][(Cp*Rh)6Zn 18Cl12(μ6-Cl)] (2), both bearing closed shell 18-electron square pyramidal Cp*RhZn4 building units were obtained by combined Ga/Zn, Me/Cp* and Me/Cl exchange upon treatment of [Cp*Rh(GaCp*)2(GaCl2Cp*)] with ZnMe 2 (Cp* = pentamethylcyclopentadienyl). © 2010 The Royal Society of Chemistry.

Año de publicación:

2010

Keywords:

Fuente:

scopus