Selective reduction of aromatic ketones in aqueous medium mediated by Ti(III)/Mn: A revised mechanism
Abstract:
An experimental study on the role played by each of the reagents involved in the selective reduction of aromatic ketones in aqueous medium is reported. In this reaction, the reduction of aromatic ketones is mediated by Cp 2TiCl. Moreover, the presence of Mn in the reaction medium is mandatory. To account for these findings, a substantially revised mechanism is proposed. © 2014 American Chemical Society.
Año de publicación:
2014
Keywords:
Fuente:
scopusTipo de documento:
Article
Estado:
Acceso restringido
Áreas de conocimiento:
- Química orgánica
- Ingeniería química
Áreas temáticas:
- Química física
- Ingeniería y operaciones afines
- Química y ciencias afines
