Structure and bonding of metal-rich coordination compounds containing low valent Ga(I) and Zn(I) ligands

Abstract:

Recent developments in the field of metal-rich low valent metal complexes with gallium(I)/zinc(I) ligands and their structural features are reviewed together with related theoretical calculations. Some emphasis is given to sterically encumbering NHC analogous ligands as well as the naked ions E +. The chemistry of organo Zn(I) ligands at transition metals is reviewed in the light of the recently discovered synthetic approach via suitable organo Ga(I) complexes as starting materials. © Springer-Verlag Berlin Heidelberg 2010.

Año de publicación:

2010

Keywords:

• Metal-metal bond
• Zinc(I)
• Gallium(I)
• clusters
• Main group chemistry

Fuente:

scopus

google