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Synthesis, characterization, and biphasic ionic liquid media 1-hexene hydrogenation reaction of RuCl<inf>2</inf>(DMSO)<inf>2</inf>(NC <inf>5</inf>H<inf>4</inf>CO<inf>2</inf>Na-3)<inf>2</inf>

Abstract:

RuCl2(DMSO)2(NC5H4CO 2Na-3)2 is very soluble in the ionic liquid (IL) 1-n-butyl-3-methylimidazolium tetrafluoroborate, [(BMIM)BF4]. The complex was prepared by reacting RuCl2(DMSO)4 with NC 5H4CO2Na-3, sodium nicotinate, in toluene, and was characterized by spectroscopic methods. The complex catalyzes the hydrogenation of 1-hexene (600 psi H2, 100 °C) in a two-phase system consisting of cyclohexane/[(BMIM)BF4] with 75% conversion in 24 h and modest substrate isomerization. The complex shows good stability and can be reused several times with little loss in activity. © 2011 Springer Science+Business Media B.V.

Año de publicación:

2011

Keywords:

    Fuente:

    scopusscopus
    googlegoogle

    Tipo de documento:

    Article

    Estado:

    Acceso restringido

    Áreas de conocimiento:

    • Catálisis
    • Ingeniería química

    Áreas temáticas:

    • Aceites, grasas, ceras y gases industriales
    • Química física
    • Ingeniería química

    Contribuidores:

    Fontal B.Fontal B.
    Suárez T.Suárez T.
    Fonseca Y.Fonseca Y.
    Reyes M.Reyes M.
    Joel Eduardo Vielma-PuenteJoel Eduardo Vielma-Puente
    Díaz J.Díaz J.
    Bellandi F.Bellandi F.
    Cancines P.Cancines P.