A convenient cross-metathesis approach to trisporins

Abstract:

Three series of trisporins have been prepared using a strategy in which a cross-metathesis is the key step. This reaction has proved to be highly regioselective, allowing the combination of α- or β-ionone derivatives having a 1,1-disustituted olefin with trisubstituted alkenes. The stereochemistry of the newly formed olefins has been established by spectroscopic means. © 2009 Elsevier Ltd. All rights reserved.

Año de publicación:

2009

Keywords:

Fuente:

scopus