The reaction of RhCp*(CH<inf>3</inf>)<inf>2</inf>(L) (L = pyridine, dmso) with GaCp* and AlCp*: A new type of carbon-carbon bond activation reaction

Abstract:

Reaction of RhCp*(L)(CH3)2 (L = pyridine, dmso) with equimolar amounts of GaCp* at 60°C quantitatively leads to the zwitterionic species [Cp*Rh(CpMe4GaMe3)]. [Cp*Rh(CH3)2(GaCp*)] could be isolated and identified as an intermediate in this reaction.

Año de publicación:

2004

Keywords:

Fuente:

scopus

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