Towards dipyrrins: Oxidation and metalation of acyclic and macrocyclic Schiff-base dipyrromethanes

Abstract:

Oxidation of acyclic Schiff-base dipyrromethanes cleanly results in dipyrrins, whereas the macrocyclic 'Pacman' analogues either decompose or form new dinuclear copper(ii) complexes that are inert to ligand oxidation; the unhindered hydrogen substituent at the meso-carbon allows new structural motifs to form.

Año de publicación:

2015

Keywords:

Fuente:

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scopus