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Compaction of porous ices rich in water by swift heavy ions

Abstract:

Porous water ice and water ice mixtures H2O:X (X=CO, CO2 and CH4) produced at 15K, with film thicknesses in the 0.5-1μm range, were irradiated by swift ions and monitored by mid-infrared spectroscopy (FTIR). The analysis of the evolution of the pure water ice infrared absorption on ion beam dose reveals a strong correlation among three quantities: (i) the absorbance of the most intense band (3250cm-1), (ii) the wavelength of the maximum absorbance of this band and (iii) the absorbance of the OH-dangling bonds. This correlation is interpreted as indications of the water ice compaction by irradiation: as the beam fluence increases, the ice porosity decreases, the dangling bond peaks collapse and the area and position of the 3250cm-1 band vary exponentially, all of them evolving with the same compaction cross section (σc). The linear dependence σc∝Se (Se being the electronic stopping power) is observed for both pure and mixed water ices, confirming previous results. We suggests that the infrared absorption A-value varies with dose as (1-ζe-D/D0) during the compaction process (D0=0.2eV/molec being the effective energy density to eliminate the OH-db, and ζ is a parameter characterizing the porosity). These findings may be used as a diagnostic tool to probe the morphology of water ices occurring in the outer Solar System and in the ISM.