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Angewandte Chemie - International Edition(1)
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Catalytic epoxypolyene cyclization via radicals: Highly diastereoselective formal synthesis of puupehedione and 8-epi-puupehedione
ArticleAbstract: A catalytic and highly stereoselective synthesis of a common building block for the marine natural pPalabras claves:Catalysis, Cuprates, Epoxypolyene cyclization, Natural productsAutores:Antonio Rosales Martínez, Gansäuer A., Justicia J.Fuentes:scopusTransition-metal-catalyzed allylic substitution and titanocene-catalyzed epoxypolyene cyclization as a powerful tool for the preparation of terpenoids
ArticleAbstract: Many biologically active substances are composed of sesquiterpene units linked to aromatic structurePalabras claves:Copper, Cyclization, Epoxides, radicals, titaniumAutores:Antonio Rosales Martínez, Cuerva J.M., Gansäuer A., Justicia J., Oltra J.E., Rinker B., Worgull D.Fuentes:scopusWater: The ideal hydrogen-atom source in free-radical chemistry mediated by Ti<sup>III</sup> and other single-electron-transfer metals?
ArticleAbstract: (Chemical Equation Presented) Hydrogen-atom transfer from water to free radicals can be mediated byPalabras claves:Epoxides, hydrogen transfer, radicals, titanium, WATERAutores:Antonio Rosales Martínez, Buñuel E., Campaña A., Cárdenas D., Cuerva J.M., Justicia J., Oller-López J.L., Oltra J.E., Robles R.Fuentes:scopus