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Catalytic epoxypolyene cyclization via radicals: Highly diastereoselective formal synthesis of puupehedione and 8-epi-puupehedione
ArticleAbstract: A catalytic and highly stereoselective synthesis of a common building block for the marine natural pPalabras claves:Catalysis, Cuprates, Epoxypolyene cyclization, Natural productsAutores:Antonio Rosales Martínez, Gansäuer A., Justicia J.Fuentes:scopusEfficient and stereoselective synthesis of precursors for epoxypolyene cyclizations via allylic substitutions
ArticleAbstract: A catalytic and highly stereoselective approach to precursors for epoxypolyene cyclizations based onPalabras claves:Catalysis, Cuprates, Epoxides, Epoxypolyene cyclization, Grignard ReagentAutores:Antonio Rosales Martínez, Gansäuer A., Justicia J., Rinker B.Fuentes:scopusTitanocene-catalysed, selective reduction of ketones in aqueous media. A safe, mild, inexpensive procedure for the synthesis of secondary alcohols via radical chemistry
ArticleAbstract: We report here a novel procedure for the reduction of ketones to secondary alcohols using catalyticPalabras claves:electron transfer, Free radicals, homogeneous catalysis, Ketones, titaniumAutores:Antonio Rosales Martínez, Barrero A.F., Cuerva J.M., Gansäuer A., Oltra J.E.Fuentes:scopusTransition-metal-catalyzed allylic substitution and titanocene-catalyzed epoxypolyene cyclization as a powerful tool for the preparation of terpenoids
ArticleAbstract: Many biologically active substances are composed of sesquiterpene units linked to aromatic structurePalabras claves:Copper, Cyclization, Epoxides, radicals, titaniumAutores:Antonio Rosales Martínez, Cuerva J.M., Gansäuer A., Justicia J., Oltra J.E., Rinker B., Worgull D.Fuentes:scopus