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"Naked" Ga<sup>+</sup> and In<sup>+</sup> as pure acceptor ligands: Structure and bonding of [GaPt(GaCp*)<inf>4</inf>][BAr <sup>F</sup>]
ArticleAbstract: In the buff: The reaction of [Pt(GaCp*)4] with the Ga + source [Ga2Cp*][BArF] (Cp* = C5Me5; BArF = BPalabras claves:Density functional calculations, Gallium, Group 13 elements, metalloids, PlatinumAutores:Buchin B., Fernandez I., Fischer R.A., Frenking G., Gemel C., Thomas CadenbachFuentes:scopusErratum: Syntheses and crystal structures of ruthenium and rhodium olefin complexes containing GaCp<sup>*</sup> (Inorganic Chemistry (2009) 48 (5026) DOI: 10.1021/ic802283r)
OtherAbstract:Palabras claves:Autores:Bollermann T., Fischer R.A., Gemel C., Thomas CadenbachFuentes:scopusErratum: The [Ga<inf>2</inf>(C<inf>5</inf>Me<inf>5</inf>)]<sup>+</sup> Ion: Bipyramidal double-cone structure and weakly coordinated, monovalent Ga <sup>+</sup> (Agewandte Chemie-International Edition (2006) 45 (1074-1076))
OtherAbstract:Palabras claves:Autores:Buchin B., Fischer R.A., Gemel C., Schmid R., Thomas CadenbachFuentes:scopusOne electron organozinc ligands in metal rich molecules by Ga/Zn exchange: From Cp*Rh(GaCp*)<inf>2</inf> to Cp*Rh(ZnR)<inf>4</inf> units
ArticleAbstract: Two unusual compounds, [{Cp*Rh(ZnCp*)2(ZnMe)(ZnCl)} 2] (1) and [Cp*2Rh][(Cp*Rh)6Zn 18Cl12(μ6-Cl)] (2Palabras claves:Autores:Bollermann T., Fischer R.A., Gemel C., Molon M., Thomas CadenbachFuentes:scopusOrganometallic chemistry of Ga<sup>+</sup>: Formation of an unusual gallium dimer in the coordination sphere of ruthenium
ArticleAbstract: New insights into the distinct organometallic chemistry of the Ga + ion are presented. Ga+ reacts asPalabras claves:Density functional calculations, Gallium, Low-valent ion, metal-metal interactions, rutheniumAutores:Bollermann T., Fernandez I., Fischer R.A., Frenking G., Gemel C., Thomas CadenbachFuentes:googlescopusMechanistic insights into an unprecedented C-C bond activation on a Rh/Ga bimetallic complex: A combined experimental/computational approach
ArticleAbstract: The unusual rearrangement of [RhCp*(GaCp*)(CH3) 2] (1c) to [RhCp*(C5Me4Ga(CH 3)3)] (2) is presentedPalabras claves:Autores:Fischer R.A., Gemel C., Schmid R., Thomas CadenbachFuentes:googlescopusMethylgallium as a terminal ligand in [(Cp*Ga) <inf>4</inf>Rh(GaCH<inf>3</inf>)]<sup>+</sup>
ArticleAbstract: (Chemical Presented) The smallest possible gallium alkyl species, the otherwise elusive GaCH3, has bPalabras claves:Carbenoids, Gallium, Metal ligands, Oxidation states, RhodiumAutores:Fischer R.A., Gemel C., Thomas Cadenbach, Zacher D.Fuentes:googlescopusMolecular alloys, linking organometallics with intermetallic Hume-Rothery phases: The highly coordinated transition metal compounds [M(ZnR)<inf>n</inf>] (n ≥ 8) containing organo-zinc ligands
ArticleAbstract: This paper presents the preparation, characterization and bonding analyses of the closed shell 18 elPalabras claves:Autores:Bollermann T., Fernandez I., Fischer R.A., Frenking G., Gemel C., Thomas Cadenbach, Tombul M., Von Hopffgarten M.Fuentes:scopusMolecular alloys: Experimental and theoretical investigations on the substitution of zinc by cadmium and mercury in the homologous series [Mo(M′R)<inf>12</inf>] and [M(M′R)<inf>8</inf>] (M=Pd, Pt; M′=Zn, Cd, Hg)
ArticleAbstract: The synthesis and structural characterization of novel, metal-rich, highly coordinated compounds [MoPalabras claves:bonding analysis, Cadmium, cluster compounds, coordination compounds, ZincAutores:Bollermann T., Fischer R.A., Frenking G., Gemel C., Thomas Cadenbach, Vona Hopffgarten M.Fuentes:scopusMolecular cut-outs of Mo/Zn hume-rothery phases: Synthesis and structure of [{Mo(CO)<inf>4</inf>}<inf>4</inf>(Zn)<inf>6</inf>(μ-ZnCp*) <inf>4</inf>]
ArticleAbstract: Zinc in the middle: The reaction of [Mo-(GaCp*)2(CO) 4] and Zn(CH3)2 results in the cluster [{Mo(CO)Palabras claves:cluster compounds, Coordination chemistry, Gallium, Molybdenum, ZincAutores:Fischer R.A., Gemel C., Thomas CadenbachFuentes:scopus