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scopus(15)
An improved synthesis of Kagan's menthyl substituted titanocene and zirconocene dichloride, comparison of their crystal structures, and preliminary catalyst evaluation
OtherAbstract: An improved synthesis of 1 and 2 is described that allows access to these complexes in multigram quaPalabras claves:Carbometallation, Catalysis, Crystal structure, titanium, ZirconiumAutores:Antonio Rosales Martínez, Bluhm H., Cuerva J.M., Gansäuer A., Narayan S., Nieger M., Oltra J.E., Schiffer-Ndene N.Fuentes:scopusCp<inf>2</inf> TiCl/D<inf>2</inf> O/Mn, a formidable reagent for the deuteration of organic compounds
ReviewAbstract: Cp2 TiCl/D2 O/Mn is an efficient combination, sustainable and cheap reagent that mediates the D-atomPalabras claves:Deuteration, Deuterium atom transfer, Radical and/or organometallic chemistry, TitanoceneAutores:Antonio Rosales Martínez, Rodríguez-García I.Fuentes:scopusCp<inf>2</inf>TiCl is a useful reagent to teach multidisciplinary chemistry
ReviewAbstract: Cp2TiCl is a single electron transfer reagent which has contributed to several field of scientific kPalabras claves:Chemical Engineering, Discovery learning, Green Chemistry, Multidisciplinary chemistry, TitanoceneAutores:Antonio Rosales MartínezFuentes:scopusErratum: Water: The ideal hydrogen-atom source in free-radical chemistry mediated by Ti<sup>III</sup> and other single-electron-transfer metals? (Angewandte Chemie - International Edition (2006) 45, (5522-5526) DOI: 10.1002/anie.200600831)
OtherAbstract:Palabras claves:Autores:Antonio Rosales Martínez, Buñuel E., Campaña A., Cárdenas D., Cuerva J.M., Justicia J., Oller-López J.L., Oltra J.E., Robles R.Fuentes:scopusEffects of solvents and water in Ti(III)-mediated radical cyclizations of epoxygermacrolides. Straightforward synthesis and absolute stereochemistry of (+)-3α-hydroxyreynosin and related eudesmanolides
ArticleAbstract: The Cp2TiCl-mediated rearrangement of 1,10-epoxy-11β,13-dihydrocostunolide (4) was carried out usingPalabras claves:Autores:Antonio Rosales Martínez, Barrero A.F., Cuerva J.M., Enrique Oltra J.Fuentes:scopusHighly selective barbier-type propargylations and allenylations catalyzed by titanocene(III)
ArticleAbstract: The alkyne functional group is found in many bioactive natural products and is the key to many imporPalabras claves:Allenes, carbonyl compounds, homogeneous catalysis, propargylations, titaniumAutores:Álvarez-Manzaneda E., Antonio Rosales Martínez, Muñoz-Bascón J., Oltra J.E., Sancho-Sanz I.Fuentes:scopusSelective reduction of aromatic ketones in aqueous medium mediated by Ti(III)/Mn: A revised mechanism
ArticleAbstract: An experimental study on the role played by each of the reagents involved in the selective reductionPalabras claves:Autores:Antonio Rosales Martínez, Gansäuer A., Mayra A. Castañeda, Muñoz-Bascón J., Oltra J.E., Padial N.M., Rodríguez-García I., Roldan-Molina E.Fuentes:scopusReduction of furfural by Mn/2,4,6-Coll<sup>.</sup>HCl/H<inf>2</inf>O: Mechanistic aspects of this reaction
ArticleAbstract:Palabras claves:furfural, Furfuryl alcohol, Green Chemistry, manganese, reduction reactionAutores:Antonio Rosales Martínez, Castro Rodríguez M., Cordobés Carmona F., Díaz Ojeda E., Enríquez L., Jaraíz M., Pozo-Morales L., Roman Nicolay Rodríguez-MaeckerFuentes:scopusTi-Catalyzed Synthesis of Exocyclic Allenes on Oxygen Heterocycles
ArticleAbstract: A general method for the straightforward synthesis of exocyclic allenes on five-, six-, seven-, andPalabras claves:Allenes, Cyclization, homogeneous catalysis, Oxygen heterocycles, titanium, TitanoceneAutores:Alvarez-Corral M., Antonio Rosales Martínez, García-Martínez M., Hernández-Cervantes C., Muñoz-Bascón J., Muñoz-Dorado M., Oltra J.E., Padial N.M., Rodríguez-García I., Roldan-Molina E., Ruiz-Muelle A.B.Fuentes:scopusTi-catalyzed homolytic opening of ozonides: A sustainable C-C bond-forming reaction
ArticleAbstract: The unprecedented homolytic opening of ozonides promoted and catalyzed by titanocene(III) is reportePalabras claves:Autores:Alvarez-Corral M., Antonio Rosales Martínez, López-Sánchez C., Muñoz-Bascón J., Muñoz-Dorado M., Oltra J.E., Rodríguez-García I.Fuentes:scopus