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Effects of solvents and water in Ti(III)-mediated radical cyclizations of epoxygermacrolides. Straightforward synthesis and absolute stereochemistry of (+)-3α-hydroxyreynosin and related eudesmanolides
ArticleAbstract: The Cp2TiCl-mediated rearrangement of 1,10-epoxy-11β,13-dihydrocostunolide (4) was carried out usingPalabras claves:Autores:Antonio Rosales Martínez, Barrero A.F., Cuerva J.M., Enrique Oltra J.Fuentes:scopusSelective reduction of aromatic ketones in aqueous medium mediated by Ti(III)/Mn: A revised mechanism
ArticleAbstract: An experimental study on the role played by each of the reagents involved in the selective reductionPalabras claves:Autores:Antonio Rosales Martínez, Gansäuer A., Mayra A. Castañeda, Muñoz-Bascón J., Oltra J.E., Padial N.M., Rodríguez-García I., Roldan-Molina E.Fuentes:scopusSynthesis of (+)-8-deoxyvernolepin and its 11,13-dihydroderivative. A novel reaction initiated by sulfene elimination leads to the 2-oxa-cis-decalin skeleton
ArticleAbstract: The title compounds are interesting candidates for antifungal screening. This paper describes the enPalabras claves:Autores:Álvarez M., Antonio Rosales Martínez, Barrero A.F., Oltra J.E.Fuentes:scopusSynthesis of (±)-aureol by bioinspired rearrangements
ArticleAbstract: A bioinspired and sustainable procedure for the straightforward synthesis of (±)-aureol has been achPalabras claves:Autores:Antonio Rosales Martínez, Muñoz-Bascón J., Oltra J.E., Padial N.M., Rivas-Bascón N., Rodríguez-García I., Roldan-Molina E., Roman Nicolay Rodríguez-MaeckerFuentes:scopusThe Proven Versatility of Cp<inf>2</inf>TiCl
ArticleAbstract: In the last two decades, titanocene monochloride has been postulated as a monoelectronic transfer rePalabras claves:Autores:Antonio Rosales Martínez, Morales L.P., Ojeda E.D., Rodríguez M.C., Rodríguez-García I.Fuentes:scopusTi-catalyzed homolytic opening of ozonides: A sustainable C-C bond-forming reaction
ArticleAbstract: The unprecedented homolytic opening of ozonides promoted and catalyzed by titanocene(III) is reportePalabras claves:Autores:Alvarez-Corral M., Antonio Rosales Martínez, López-Sánchez C., Muñoz-Bascón J., Muñoz-Dorado M., Oltra J.E., Rodríguez-García I.Fuentes:scopus