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Reactivity of dirhenium and triruthenium carbonyls toward a biphosphole ligand: M–M, P–P and C–H bonds cleavage
ArticleAbstract: The reaction of [Re2(CO)8(CH3CN)2] with bis(2-thienyl)biphosphole in refluxing n-octane affords thePalabras claves:Biphosphole, C-H activation, Metal-metal and phosphorus-phosphorus bonds cleavage, Tetranuclear cluster, η -phospholyl complex 5Autores:Arce A.J., David Santiago Coll, Edward E. Ávila, Fuentes F., Gonzalez T., Hissler M., MacHado R.A., Peña D., Réau R., Yomaira OteroFuentes:googlescopusSynthesis and characterization of rhodium complexes with phosphine-stabilized germylenes
ArticleAbstract: The reaction of phosphine-stabilized germylenes (1a,b) with dimer complex [Rh 2(μ-Cl) 2(COD) 2] leadPalabras claves:Autores:Baceiredo A., Bricẽo A., David Santiago Coll, Garcia J.M., Kato T., Ocando-Mavárez E., Saffon-Merceron N.Fuentes:scopusSynthesis, characterization and biological activity of platinum(II) complexes with a tetrapyrazole ligand
ArticleAbstract: In the search of an effective chemotherapy for the treatment of cancer, in this work we describe thePalabras claves:anticancer activity, DNA, Platinum complexes, Tetrapyrazole ligand, Thioredoxin reductaseAutores:Capote J., Castro W., David Santiago Coll, Fernández-Mestre M., Hernández-Medina F., Higuera-Padilla A.R., Karam A.R., Ortega D., Rodriguez B., Rodriguez-Cordero M., Taylor P., Urdanibia I.Fuentes:scopusSynthesis, characterization and reactivity of dinuclear rhenium complexes containing hemilabile phosphines as ligands: X-ray structures of diax-[Re<inf>2</inf>(CO)<inf>8</inf>{κ<sup>1</sup>(P)-Ph<inf>2</inf>P(CH<inf>2</inf>)<inf>2</inf>CN}<inf>2</inf>], [Re<inf>2</inf>(CO)<inf>8</inf>{μ:κ<sup>3</sup>(P,C,C)-<sup>i</sup>Pr<inf>2</inf>NP(CH<inf>2</inf>CH=CH<inf>2</inf>)<inf>2</inf>}] and diax-[Re<inf>2</inf>(CO)<inf>8</inf>(PPh<inf>3</inf>){κ<sup>1</sup>(P)-p-MeOC<inf>6</inf>H<inf>4</inf>P(CH<inf>2</inf>CH=CH<inf>2</inf>)<inf>2</inf>}]
ArticleAbstract: The reaction of [Re2(CO)8(MeCN)2] with cyanoethylphosphines affords mono- and disubstituted compoundPalabras claves:Diallylphosphines, Dinuclear rhenium, Dirhenium carbonyls, Hemilability, IsomerismAutores:Arce A.J., David Santiago Coll, Garcia J.M., Gonzalez T., MacHado R.A., Ocando-Mavárez E., Peña D., Yomaira OteroFuentes:scopus