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Inorganica Chimica Acta(4)
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Chemistry of transition-metal complexes containing functionalized phosphines. Part 2. Cationic rhodium(I) complexes stabilized by hemilabile diallylphosphines
ArticleAbstract: Cationic rhodium(I) complexes of the type [Rh(COD){κ3(P,C, C)-RP(CH2CHCH2)2}][BF4] (R = tBu 3a, Ph 3Palabras claves:Diallylphosphines, Hemilabile properties, Hybrid ligands, Ligand exchange reactionAutores:Ascanio J., Atencio R., Bricẽo A., David Santiago Coll, Edward E. Ávila, Garcia J.M., Gonzalez T., Ocando-Mavárez E., Pekerar S.V., Rosales M.Fuentes:googlescopusA novel tetramer copper(I) complex containing diallylphosphine ligands: Synthesis, characterization and catalytic application in A<sup>3</sup>-coupling (Aldehyde-Amine-Alkyne) reactions
ArticleAbstract: A novel tetrameric copper(I) complex containing tert-butyldiallylphosphine ligands, [CuCl{tBu-P(CH2CPalabras claves:A -coupling reactions 3, Diallylphosphine ligands, Propargylamine, Tetramer cobre(I) complexAutores:David Santiago Coll, Edward E. Ávila, Garcia J.M., Gonzalez T., Ocando-Mavárez E., Rosales J.Fuentes:googlescopusA simple method for the determination of the Tolman electronic parameter of different phosphorus containing ligands, by means of the average local ionization energy
ArticleAbstract: Abstract The average local ionization energy (I(r)) was tested as a theoretical descriptor of the ToPalabras claves:Average local ionization energy, Cone angle, Electrostatic potential, Phosphines and Phosphites basicity, Tolman electronic parameterAutores:Alba Beatriz Vidal, Añez R., David Santiago Coll, Ocando-Mavárez E., Rodríguez J.A., Sierraalta A.Fuentes:scopusFluxional behaviour of phosphole and phosphine ligands on triosmium clusters
ArticleAbstract: The unsaturated cluster [Os<inf>3</inf>(μ-H)<inf>2</inf>(CO)<inf>10</inf>] reacts with a variety ofPalabras claves:Fluxional behavior, Mono- and disubstituted triosmium, Phosphine, Phosphole, Unsaturated osmium clusterAutores:Arce A.J., De Sanctis Y., Gonzalez T., Hissler M., MacHado R.A., Ocando-Mavárez E., Peña D., Réau R., Yomaira OteroFuentes:scopusSingle and double A<sup>3</sup>-coupling (aldehyde-amine-alkyne) reaction catalyzed by an air stable copper(I)-phosphole complex
ArticleAbstract: An air stable copper(I)-phosphole complex, [CuCl{2,5-bis(2-thienyl)-1-phenylphosphole}2] (1), was utPalabras claves:A -coupling reaction 3, Copper(I) complex, Phosphole, PropargylamineAutores:Arce A.J., Cammarata J.R., Fuentes F., Garcia J.M., Ocando-Mavárez E., Rivera R., Yomaira OteroFuentes:scopusReactivity of triosmium clusters with 3,4-dimethyl-1-phenylphosphole and cyanoethyldi-tert-butylphosphine ligands: X-ray crystal structures of [Os <inf>3</inf>(CO)<inf>9</inf>(μ-OH)(μ-H)(η<sup>1</sup>-PhPC <inf>4</inf>H<inf>2</inf>Me<inf>2</inf>)] and [Os<inf>3</inf>(CO) <inf>11</inf>(η<sup>1</sup>- <sup>t</sup> Bu<inf>2</inf>PC<inf>2</inf>H <inf>4</inf>CN)]
ArticleAbstract: Reaction of [Os3(μ-H)2(CO)10] with 3,4-dimethyl-1-phenylphosphole in refluxing cyclohexane affords tPalabras claves:Autores:Arce A.J., De Sanctis Y., Gonzalez T., MacHado R.A., Ocando-Mavárez E., Peña D., Yomaira OteroFuentes:scopusSynthesis and characterization of rhodium complexes with phosphine-stabilized germylenes
ArticleAbstract: The reaction of phosphine-stabilized germylenes (1a,b) with dimer complex [Rh 2(μ-Cl) 2(COD) 2] leadPalabras claves:Autores:Baceiredo A., Bricẽo A., David Santiago Coll, Garcia J.M., Kato T., Ocando-Mavárez E., Saffon-Merceron N.Fuentes:scopusSynthesis, characterization and reactivity of dinuclear rhenium complexes containing hemilabile phosphines as ligands: X-ray structures of diax-[Re<inf>2</inf>(CO)<inf>8</inf>{κ<sup>1</sup>(P)-Ph<inf>2</inf>P(CH<inf>2</inf>)<inf>2</inf>CN}<inf>2</inf>], [Re<inf>2</inf>(CO)<inf>8</inf>{μ:κ<sup>3</sup>(P,C,C)-<sup>i</sup>Pr<inf>2</inf>NP(CH<inf>2</inf>CH=CH<inf>2</inf>)<inf>2</inf>}] and diax-[Re<inf>2</inf>(CO)<inf>8</inf>(PPh<inf>3</inf>){κ<sup>1</sup>(P)-p-MeOC<inf>6</inf>H<inf>4</inf>P(CH<inf>2</inf>CH=CH<inf>2</inf>)<inf>2</inf>}]
ArticleAbstract: The reaction of [Re2(CO)8(MeCN)2] with cyanoethylphosphines affords mono- and disubstituted compoundPalabras claves:Diallylphosphines, Dinuclear rhenium, Dirhenium carbonyls, Hemilability, IsomerismAutores:Arce A.J., David Santiago Coll, Garcia J.M., Gonzalez T., MacHado R.A., Ocando-Mavárez E., Peña D., Yomaira OteroFuentes:scopus