Mostrando 9 resultados de: 9
Filtros aplicados
Subtipo de publicación
Article(9)
Publisher
Inorganica Chimica Acta(4)
Journal of Organometallic Chemistry(2)
Inorganic Chemistry(1)
Tetrahedron Letters(1)
Transition Metal Chemistry(1)
Área temáticas
Química inorgánica(8)
Química orgánica(6)
Química analítica(2)
Química física(2)
Técnicas, equipos y materiales(1)
Área de conocimiento
Química inorgánica(5)
Ciencia de materiales(4)
Catálisis(2)
Química general(2)
Cristalografía de rayos X(1)
Origen
google(2)
Chemistry of transition-metal complexes containing functionalized phosphines. Part 2. Cationic rhodium(I) complexes stabilized by hemilabile diallylphosphines
ArticleAbstract: Cationic rhodium(I) complexes of the type [Rh(COD){κ3(P,C, C)-RP(CH2CHCH2)2}][BF4] (R = tBu 3a, Ph 3Palabras claves:Diallylphosphines, Hemilabile properties, Hybrid ligands, Ligand exchange reactionAutores:Ascanio J., Atencio R., Bricẽo A., David Santiago Coll, Edward E. Ávila, Garcia J.M., Gonzalez T., Ocando-Mavárez E., Pekerar S.V., Rosales M.Fuentes:googlescopusA novel tetramer copper(I) complex containing diallylphosphine ligands: Synthesis, characterization and catalytic application in A<sup>3</sup>-coupling (Aldehyde-Amine-Alkyne) reactions
ArticleAbstract: A novel tetrameric copper(I) complex containing tert-butyldiallylphosphine ligands, [CuCl{tBu-P(CH2CPalabras claves:A -coupling reactions 3, Diallylphosphine ligands, Propargylamine, Tetramer cobre(I) complexAutores:David Santiago Coll, Edward E. Ávila, Garcia J.M., Gonzalez T., Ocando-Mavárez E., Rosales J.Fuentes:googlescopusA simple method for the determination of the Tolman electronic parameter of different phosphorus containing ligands, by means of the average local ionization energy
ArticleAbstract: Abstract The average local ionization energy (I(r)) was tested as a theoretical descriptor of the ToPalabras claves:Average local ionization energy, Cone angle, Electrostatic potential, Phosphines and Phosphites basicity, Tolman electronic parameterAutores:Alba Beatriz Vidal, Añez R., David Santiago Coll, Ocando-Mavárez E., Rodríguez J.A., Sierraalta A.Fuentes:scopusFluxional behaviour of phosphole and phosphine ligands on triosmium clusters
ArticleAbstract: The unsaturated cluster [Os<inf>3</inf>(μ-H)<inf>2</inf>(CO)<inf>10</inf>] reacts with a variety ofPalabras claves:Fluxional behavior, Mono- and disubstituted triosmium, Phosphine, Phosphole, Unsaturated osmium clusterAutores:Arce A.J., De Sanctis Y., Gonzalez T., Hissler M., MacHado R.A., Ocando-Mavárez E., Peña D., Réau R., Yomaira OteroFuentes:scopusSingle and double A<sup>3</sup>-coupling (aldehyde-amine-alkyne) reaction catalyzed by an air stable copper(I)-phosphole complex
ArticleAbstract: An air stable copper(I)-phosphole complex, [CuCl{2,5-bis(2-thienyl)-1-phenylphosphole}2] (1), was utPalabras claves:A -coupling reaction 3, Copper(I) complex, Phosphole, PropargylamineAutores:Arce A.J., Cammarata J.R., Fuentes F., Garcia J.M., Ocando-Mavárez E., Rivera R., Yomaira OteroFuentes:scopusReactivity of triosmium clusters with 3,4-dimethyl-1-phenylphosphole and cyanoethyldi-tert-butylphosphine ligands: X-ray crystal structures of [Os <inf>3</inf>(CO)<inf>9</inf>(μ-OH)(μ-H)(η<sup>1</sup>-PhPC <inf>4</inf>H<inf>2</inf>Me<inf>2</inf>)] and [Os<inf>3</inf>(CO) <inf>11</inf>(η<sup>1</sup>- <sup>t</sup> Bu<inf>2</inf>PC<inf>2</inf>H <inf>4</inf>CN)]
ArticleAbstract: Reaction of [Os3(μ-H)2(CO)10] with 3,4-dimethyl-1-phenylphosphole in refluxing cyclohexane affords tPalabras claves:Autores:Arce A.J., De Sanctis Y., Gonzalez T., MacHado R.A., Ocando-Mavárez E., Peña D., Yomaira OteroFuentes:scopusSynthesis and characterization of rhodium complexes with phosphine-stabilized germylenes
ArticleAbstract: The reaction of phosphine-stabilized germylenes (1a,b) with dimer complex [Rh 2(μ-Cl) 2(COD) 2] leadPalabras claves:Autores:Baceiredo A., Bricẽo A., David Santiago Coll, Garcia J.M., Kato T., Ocando-Mavárez E., Saffon-Merceron N.Fuentes:scopusSynthesis and characterization of trinuclear osmium clusters containing diallylphosphines as hemilabile ligands: Experimental and theoretical studies of their reactivity with nucleophilic molecules
ArticleAbstract: A series of [Os3(CO)12] phosphine substituted derivatives containing alkenylphosphine ligands has bePalabras claves:Allene insertion, Diallylphosphines, Hemilabile phosphines, Triosmium carbonylsAutores:Arce A.J., De Sanctis Y., Díaz L., Garcia J.M., Gonzalez T., MacHado R.A., Ocando-Mavárez E., Peña D., Yomaira OteroFuentes:scopusSynthesis, characterization and reactivity of dinuclear rhenium complexes containing hemilabile phosphines as ligands: X-ray structures of diax-[Re<inf>2</inf>(CO)<inf>8</inf>{κ<sup>1</sup>(P)-Ph<inf>2</inf>P(CH<inf>2</inf>)<inf>2</inf>CN}<inf>2</inf>], [Re<inf>2</inf>(CO)<inf>8</inf>{μ:κ<sup>3</sup>(P,C,C)-<sup>i</sup>Pr<inf>2</inf>NP(CH<inf>2</inf>CH=CH<inf>2</inf>)<inf>2</inf>}] and diax-[Re<inf>2</inf>(CO)<inf>8</inf>(PPh<inf>3</inf>){κ<sup>1</sup>(P)-p-MeOC<inf>6</inf>H<inf>4</inf>P(CH<inf>2</inf>CH=CH<inf>2</inf>)<inf>2</inf>}]
ArticleAbstract: The reaction of [Re2(CO)8(MeCN)2] with cyanoethylphosphines affords mono- and disubstituted compoundPalabras claves:Diallylphosphines, Dinuclear rhenium, Dirhenium carbonyls, Hemilability, IsomerismAutores:Arce A.J., David Santiago Coll, Garcia J.M., Gonzalez T., MacHado R.A., Ocando-Mavárez E., Peña D., Yomaira OteroFuentes:scopus