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A novel tetramer copper(I) complex containing diallylphosphine ligands: Synthesis, characterization and catalytic application in A<sup>3</sup>-coupling (Aldehyde-Amine-Alkyne) reactions
ArticleAbstract: A novel tetrameric copper(I) complex containing tert-butyldiallylphosphine ligands, [CuCl{tBu-P(CH2CPalabras claves:A -coupling reactions 3, Diallylphosphine ligands, Propargylamine, Tetramer cobre(I) complexAutores:David Santiago Coll, Edward E. Ávila, Garcia J.M., Gonzalez T., Ocando-Mavárez E., Rosales J.Fuentes:googlescopusCrotofolane diterpenoids from Croton caracasanus
ArticleAbstract: Four new crotofolane-type diterpenoids, crotocarasin (A-D) (1-4), together with the known crotofolinPalabras claves:Crotofolanes, Croton caracasanus Pittier, Diterpenoids, euphorbiaceaeAutores:Alírica Isabel Suárez, Bricẽo A., Chavez K., Compagnone R.S., Gonzalez T., Landaeta C., Riina R., Soscun H.J., Squitieri E.Fuentes:scopusFluxional behaviour of phosphole and phosphine ligands on triosmium clusters
ArticleAbstract: The unsaturated cluster [Os<inf>3</inf>(μ-H)<inf>2</inf>(CO)<inf>10</inf>] reacts with a variety ofPalabras claves:Fluxional behavior, Mono- and disubstituted triosmium, Phosphine, Phosphole, Unsaturated osmium clusterAutores:Arce A.J., De Sanctis Y., Gonzalez T., Hissler M., MacHado R.A., Ocando-Mavárez E., Peña D., Réau R., Yomaira OteroFuentes:scopusEthylene polymerization by binuclear chromium complex with tetrakis(pyrazolyl-methyl)benzene ligand
ArticleAbstract: Abstract: The reaction of one equivalent of 1,2,4,5-tetrakis(pyrazolyl-methyl)benzene ligand (L) witPalabras claves:1,2,4,5-Tetrakis(pyrazolyl-methyl)benzene, Binuclear chromium complex, Polyethylene, Polymer catalystAutores:David Santiago Coll, Gonzalez T., Karam A.R., Martínez I., Morales-Verdejo C., Rodríguez B.E., Rojas R.Fuentes:scopusN-Carbamoyl-Piperidine-4-Carboxylic Acid: An X-ray and Density Functional Tight-Binding Studies
ArticleAbstract: The compound N-carbamoyl-piperidine-4-carbocylic acid was synthesized and characterized by FT-IR andPalabras claves:Crystal structure, DFTB calculation, Hydrogen bonds, N-carbamoylAutores:Bricẽo A., Chacón C., Delgado G.E., Edward E. Ávila, Gonzalez T., Mora A.J.Fuentes:googlescopusHigh versatility of 3,4-dimethyl-1-phenyl-phosphole and 3-methyl-1-phenyl-phosphole as ligands in the reaction with [Re 2(CO)8(CH3CN)2] and [Ru3(CO)12]: X-ray structures of [Re2(CO)7(1:2:2-PhPC 4H2Me2)], [Re2(CO)7(1:2:2-PhPC4H3Me)] and [Ru2(CO)4(PhPC <inf>4</inf>H<inf>3</inf>Me)<inf>2</inf>]
ArticleAbstract: The reaction of [Re2(CO)8(CH3CN) 2] with 3,4-dimethyl-1-phenylphosphole affords three chromatographiPalabras claves:Dinuclear rhenium, Phospholes, Sandwich complexes, Triruthenium cluster, σ-π complexAutores:Arce A.J., Bricẽo A., De Sanctis Y., Goite M.C., Gonzalez T., MacHado R.A., Yomaira OteroFuentes:scopusInsertion of a phospholide unit into a metal-metal bond: Synthesis and X-ray structure of [Ru<inf>3</inf>(CO)<inf>9</inf>(μ:η<sup>1</sup>: η<sup>5</sup>-PC<inf>4</inf>H<inf>2</inf>Me<inf>2</inf>)(η<sup>1</sup>- C<inf>6</inf>H<inf>5</inf>)]
ArticleAbstract: The reaction of [Ru3(CO)12] with 3,4-dimethyl-1- phenylphosphole under mild conditions affords threePalabras claves:Phospholes, Phospholide, Triosmium clusters, Triruthenium clustersAutores:Arce A.J., De Sanctis Y., Goite M.C., Gonzalez T., MacHado R.A., Yomaira OteroFuentes:scopusIsomeric clusters [HOs <inf>3</inf>(CO) <inf>10</inf>(C <inf>18</inf>H <inf>11</inf>N <inf>6</inf>)] obtained from the reaction of [Os <inf>3</inf>(CO) <inf>10</inf>(CH <inf>3</inf>CN) <inf>2</inf>] with new tris-pyridyl-1,2,4-triazines
ArticleAbstract: The new tris-pyridyl-as-triazines 3-(3-pyridyl)-5,6-bis(2-pyridyl)-1,2,4- triazine (3TPT) and 3-(4-pPalabras claves:As-triazines, Orthometallation, Osmium clusters, Pyridynes, X-ray crystal structuresAutores:Arce A.J., De Sanctis Y., Goite M.C., Gonzalez T., MacHado R.A., Yomaira OteroFuentes:scopusReactivity of dirhenium and triruthenium carbonyls toward a biphosphole ligand: M–M, P–P and C–H bonds cleavage
ArticleAbstract: The reaction of [Re2(CO)8(CH3CN)2] with bis(2-thienyl)biphosphole in refluxing n-octane affords thePalabras claves:Biphosphole, C-H activation, Metal-metal and phosphorus-phosphorus bonds cleavage, Tetranuclear cluster, η -phospholyl complex 5Autores:Arce A.J., David Santiago Coll, Edward E. Ávila, Fuentes F., Gonzalez T., Hissler M., MacHado R.A., Peña D., Réau R., Yomaira OteroFuentes:googlescopusReactivity of triosmium clusters with 3,4-dimethyl-1-phenylphosphole and cyanoethyldi-tert-butylphosphine ligands: X-ray crystal structures of [Os <inf>3</inf>(CO)<inf>9</inf>(μ-OH)(μ-H)(η<sup>1</sup>-PhPC <inf>4</inf>H<inf>2</inf>Me<inf>2</inf>)] and [Os<inf>3</inf>(CO) <inf>11</inf>(η<sup>1</sup>- <sup>t</sup> Bu<inf>2</inf>PC<inf>2</inf>H <inf>4</inf>CN)]
ArticleAbstract: Reaction of [Os3(μ-H)2(CO)10] with 3,4-dimethyl-1-phenylphosphole in refluxing cyclohexane affords tPalabras claves:Autores:Arce A.J., De Sanctis Y., Gonzalez T., MacHado R.A., Ocando-Mavárez E., Peña D., Yomaira OteroFuentes:scopus