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A novel tetramer copper(I) complex containing diallylphosphine ligands: Synthesis, characterization and catalytic application in A<sup>3</sup>-coupling (Aldehyde-Amine-Alkyne) reactions
ArticleAbstract: A novel tetrameric copper(I) complex containing tert-butyldiallylphosphine ligands, [CuCl{tBu-P(CH2CPalabras claves:A -coupling reactions 3, Diallylphosphine ligands, Propargylamine, Tetramer cobre(I) complexAutores:David Santiago Coll, Edward E. Ávila, Garcia J.M., Gonzalez T., Ocando-Mavárez E., Rosales J.Fuentes:googlescopusChemistry of transition-metal complexes containing functionalized phosphines. Part 2. Cationic rhodium(I) complexes stabilized by hemilabile diallylphosphines
ArticleAbstract: Cationic rhodium(I) complexes of the type [Rh(COD){κ3(P,C, C)-RP(CH2CHCH2)2}][BF4] (R = tBu 3a, Ph 3Palabras claves:Diallylphosphines, Hemilabile properties, Hybrid ligands, Ligand exchange reactionAutores:Ascanio J., Atencio R., Bricẽo A., David Santiago Coll, Edward E. Ávila, Garcia J.M., Gonzalez T., Ocando-Mavárez E., Pekerar S.V., Rosales M.Fuentes:googlescopusHigh versatility of 3,4-dimethyl-1-phenyl-phosphole and 3-methyl-1-phenyl-phosphole as ligands in the reaction with [Re 2(CO)8(CH3CN)2] and [Ru3(CO)12]: X-ray structures of [Re2(CO)7(1:2:2-PhPC 4H2Me2)], [Re2(CO)7(1:2:2-PhPC4H3Me)] and [Ru2(CO)4(PhPC <inf>4</inf>H<inf>3</inf>Me)<inf>2</inf>]
ArticleAbstract: The reaction of [Re2(CO)8(CH3CN) 2] with 3,4-dimethyl-1-phenylphosphole affords three chromatographiPalabras claves:Dinuclear rhenium, Phospholes, Sandwich complexes, Triruthenium cluster, σ-π complexAutores:Arce A.J., Bricẽo A., De Sanctis Y., Goite M.C., Gonzalez T., MacHado R.A., Yomaira OteroFuentes:scopusInsertion of a phospholide unit into a metal-metal bond: Synthesis and X-ray structure of [Ru<inf>3</inf>(CO)<inf>9</inf>(μ:η<sup>1</sup>: η<sup>5</sup>-PC<inf>4</inf>H<inf>2</inf>Me<inf>2</inf>)(η<sup>1</sup>- C<inf>6</inf>H<inf>5</inf>)]
ArticleAbstract: The reaction of [Ru3(CO)12] with 3,4-dimethyl-1- phenylphosphole under mild conditions affords threePalabras claves:Phospholes, Phospholide, Triosmium clusters, Triruthenium clustersAutores:Arce A.J., De Sanctis Y., Goite M.C., Gonzalez T., MacHado R.A., Yomaira OteroFuentes:scopusIsomeric clusters [HOs <inf>3</inf>(CO) <inf>10</inf>(C <inf>18</inf>H <inf>11</inf>N <inf>6</inf>)] obtained from the reaction of [Os <inf>3</inf>(CO) <inf>10</inf>(CH <inf>3</inf>CN) <inf>2</inf>] with new tris-pyridyl-1,2,4-triazines
ArticleAbstract: The new tris-pyridyl-as-triazines 3-(3-pyridyl)-5,6-bis(2-pyridyl)-1,2,4- triazine (3TPT) and 3-(4-pPalabras claves:As-triazines, Orthometallation, Osmium clusters, Pyridynes, X-ray crystal structuresAutores:Arce A.J., De Sanctis Y., Goite M.C., Gonzalez T., MacHado R.A., Yomaira OteroFuentes:scopusSynthesis, characterization and reactivity of dinuclear rhenium complexes containing hemilabile phosphines as ligands: X-ray structures of diax-[Re<inf>2</inf>(CO)<inf>8</inf>{κ<sup>1</sup>(P)-Ph<inf>2</inf>P(CH<inf>2</inf>)<inf>2</inf>CN}<inf>2</inf>], [Re<inf>2</inf>(CO)<inf>8</inf>{μ:κ<sup>3</sup>(P,C,C)-<sup>i</sup>Pr<inf>2</inf>NP(CH<inf>2</inf>CH=CH<inf>2</inf>)<inf>2</inf>}] and diax-[Re<inf>2</inf>(CO)<inf>8</inf>(PPh<inf>3</inf>){κ<sup>1</sup>(P)-p-MeOC<inf>6</inf>H<inf>4</inf>P(CH<inf>2</inf>CH=CH<inf>2</inf>)<inf>2</inf>}]
ArticleAbstract: The reaction of [Re2(CO)8(MeCN)2] with cyanoethylphosphines affords mono- and disubstituted compoundPalabras claves:Diallylphosphines, Dinuclear rhenium, Dirhenium carbonyls, Hemilability, IsomerismAutores:Arce A.J., David Santiago Coll, Garcia J.M., Gonzalez T., MacHado R.A., Ocando-Mavárez E., Peña D., Yomaira OteroFuentes:scopusModular assembly between biimidazole complexes and chloride anions. Crystal structures of [Cu(biimidazole)<inf>2</inf>]Cl<inf>2</inf> and [Zn(Cl)(biimidazole)<inf>2</inf>]Cl
ArticleAbstract: The strong affinity of coordinated biimidazole for chloride ion via N-H⋯Cl- hydrogen bonding has beePalabras claves:Cu-complexes, Hydrogen bonding, Modular assembly, Zn-complexesAutores:Atencio R., Gonzalez T., Pedro Silva, Raḿirez K., Reyes J.A.Fuentes:scopus