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Diastereoselective Synthesis of (±)-Ambrox by Titanium(III)-Catalyzed Radical Tandem Cyclization
ArticleAbstract: A synthesis of (±)-ambrox, a compound with delicious ambergris-type scent, is presented. The key stePalabras claves:ambrox, diastereoselective synthesis, Natural products, radical chemistry, TitanoceneAutores:Antonio Rosales Martínez, Foley L.A.R., Irías-Álvarez A., Muñoz-Bascón J., Oltra J.E., Padial N.M., Pozo-Morales L., Rodríguez-García I., Roldan-Molina E., Roman Nicolay Rodríguez-Maecker, Sancho-Sanz I.Fuentes:scopusHighly selective barbier-type propargylations and allenylations catalyzed by titanocene(III)
ArticleAbstract: The alkyne functional group is found in many bioactive natural products and is the key to many imporPalabras claves:Allenes, carbonyl compounds, homogeneous catalysis, propargylations, titaniumAutores:Álvarez-Manzaneda E., Antonio Rosales Martínez, Muñoz-Bascón J., Oltra J.E., Sancho-Sanz I.Fuentes:scopusHydrogen atom donors: Recent developments
ReviewAbstract: This review highlights recent developments in the field of hydrogen atom transfer (HAT) reagents thaPalabras claves:Bond dissociation energies, Catalysis, Chain reactions, Hydrogen atom transfer, Metal-hydrogen bonds, radicalsAutores:Antonio Rosales Martínez, Gansäuer A., Huth I., Oltra J.E., Otte M., Padial N.M., Sancho-Sanz I., Shi L.Fuentes:scopus