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Catalytic epoxypolyene cyclization via radicals: Highly diastereoselective formal synthesis of puupehedione and 8-epi-puupehedione
ArticleAbstract: A catalytic and highly stereoselective synthesis of a common building block for the marine natural pPalabras claves:Catalysis, Cuprates, Epoxypolyene cyclization, Natural productsAutores:Antonio Rosales Martínez, Gansäuer A., Justicia J.Fuentes:scopusEfficient and stereoselective synthesis of precursors for epoxypolyene cyclizations via allylic substitutions
ArticleAbstract: A catalytic and highly stereoselective approach to precursors for epoxypolyene cyclizations based onPalabras claves:Catalysis, Cuprates, Epoxides, Epoxypolyene cyclization, Grignard ReagentAutores:Antonio Rosales Martínez, Gansäuer A., Justicia J., Rinker B.Fuentes:scopusTransition-metal-catalyzed allylic substitution and titanocene-catalyzed epoxypolyene cyclization as a powerful tool for the preparation of terpenoids
ArticleAbstract: Many biologically active substances are composed of sesquiterpene units linked to aromatic structurePalabras claves:Copper, Cyclization, Epoxides, radicals, titaniumAutores:Antonio Rosales Martínez, Cuerva J.M., Gansäuer A., Justicia J., Oltra J.E., Rinker B., Worgull D.Fuentes:scopusSelective reduction of aromatic ketones in aqueous medium mediated by Ti(III)/Mn: A revised mechanism
ArticleAbstract: An experimental study on the role played by each of the reagents involved in the selective reductionPalabras claves:Autores:Antonio Rosales Martínez, Gansäuer A., Mayra A. Castañeda, Muñoz-Bascón J., Oltra J.E., Padial N.M., Rodríguez-García I., Roldan-Molina E.Fuentes:scopus