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Homoleptic hexa and penta gallylene coordinated complexes of molybdenum and rhodium
ArticleAbstract: The reactions of molybdenum(0) and rhodium(I) olefin containing starting materials with the carbenoiPalabras claves:Autores:Bollermann T., Fischer R.A., Freitag K., Gemel C., Gwildies V., Molon M., Thomas CadenbachFuentes:googlescopusCo-complexation syntheses, structural characterization, and DFT studies of a novel series of polymeric alkali-metal tetraorganogallates
ArticleAbstract: Exploring the co-complexation reactions between the gallium alkyl Ga(CH2SiMe3)3 and alkali-metal alkPalabras claves:Autores:Armstrong D.R., Brammer E., Hevia E., Kennedy A.R., Thomas CadenbachFuentes:googlescopusAccessing Sodium Ferrate Complexes Containing Neutral and Anionic N-Heterocyclic Carbene Ligands: Structural, Synthetic, and Magnetic Insights
ArticleAbstract: This study reports the synthesis and single-crystal X-ray crystallographic, NMR spectroscopic, and mPalabras claves:Autores:Aromí G., Borilovic I., Hevia E., Kennedy A.R., Maddock L.C.H., Thomas CadenbachFuentes:googlescopusMacrocyclic Platforms for the Construction of Tetranuclear Oxo and Hydroxo Zinc Clusters
ArticleAbstract: The design of ligands that can act as platforms for the controlled, "bottom-up" synthesis of transitPalabras claves:Autores:Arnold P.L., Curcio M., Hofmann T.A., Love J.B., Pankhurst J.R., Thomas CadenbachFuentes:googlescopusOne electron organozinc ligands in metal rich molecules by Ga/Zn exchange: From Cp*Rh(GaCp*)<inf>2</inf> to Cp*Rh(ZnR)<inf>4</inf> units
ArticleAbstract: Two unusual compounds, [{Cp*Rh(ZnCp*)2(ZnMe)(ZnCl)} 2] (1) and [Cp*2Rh][(Cp*Rh)6Zn 18Cl12(μ6-Cl)] (2Palabras claves:Autores:Bollermann T., Fischer R.A., Gemel C., Molon M., Thomas CadenbachFuentes:scopusThe [Ga<inf>2</inf>(C<inf>5</inf>Me<inf>5</inf>)]<sup>+</sup> ion: Bipyramidal double-cone structure and weakly coordinated, monovalent Ga <sup>+</sup>
ArticleAbstract: (Figure Presented) Partial protolysis of GaCp* with [H-(OEt 2)2]+[BArF]- afforded the GaI compound [Palabras claves:Carbenoids, Cyclopentadienyl compounds, Gallium, Group 13 elementsAutores:Buchin B., Fischer R.A., Gemel C., Schmid R., Thomas CadenbachFuentes:scopusThe reaction of RhCp*(CH<inf>3</inf>)<inf>2</inf>(L) (L = pyridine, dmso) with GaCp* and AlCp*: A new type of carbon-carbon bond activation reaction
ArticleAbstract: Reaction of RhCp*(L)(CH3)2 (L = pyridine, dmso) with equimolar amounts of GaCp* at 60°C quantitativePalabras claves:Autores:Block S., Fischer R.A., Gemel C., Schmid R., Thomas CadenbachFuentes:googlescopusSubstituent-free gallium by hydrogenolysis of coordinated gaCp*: Synthesis and structure of highly fluxional [Ru<inf>2</inf>(Ga)(GaCp*) <inf>7</inf>(H)<inf>3</inf>]
ArticleAbstract: All change: Complete ligand exchange through the hydrogenation of [Ru(η4-cod)(η6-cot)] in the presenPalabras claves:cluster compounds, Coordination chemistry, Gallium, Hydrogenolysis, rutheniumAutores:Cokoja M., Fischer R.A., Gemel C., Halbherr M., Schmid R., Thomas Cadenbach, Yusenko K.Fuentes:scopusSyntheses and crystal structures of ruthenium and rhodium olefin complexes containing GaCp
ArticleAbstract: The reactivity of olefin containing complexes of the d8 metals Ru0 and Rh1 toward GaCp* and AlCp * iPalabras claves:Autores:Bollermann T., Fischer R.A., Gemel C., Thomas CadenbachFuentes:googlescopusSynthesis and structure of new compounds with Zn-Ga bonds. Insertion of the gallium(I) bisimidinate Ga(DDP) into Zn-X (X = CH<inf>3</inf>, CI) and the homoleptic complex cation [Zn(GaCp*)<inf>4</inf>]<sup>2+</sup>
ArticleAbstract: Insertion reactions of the low-valent group 13 bisimidinate ligand Ga(DDP) {DDP = 2-[(2,6-diisopropyPalabras claves:Autores:Fischer R.A., Gemel C., Kempter A., Thomas CadenbachFuentes:scopus